Hydrogen spillover as a promising strategy for boosting heterogeneous catalysis and hydrogen storage

M Li, W Yin, J Pan, Y Zhu, N Sun, X Zhang… - Chemical Engineering …, 2023 - Elsevier
Hydrogen spillover, a common active species migration phenomenon, has drawn
tremendous attention in the past few years. The spilled atomic hydrogen can not only …

Controllability construction and structural regulation of metal-organic frameworks for hydrogen storage at ambient condition: A review

W Bao, J Yu, F Chen, H Du, W Zhang, S Yan… - International Journal of …, 2023 - Elsevier
Due to the active chemical properties of hydrogen at room temperature, the efficient and safe
storage technology of hydrogen is the main bottleneck problem in the large-scale …

Defective TiOx overlayers catalyze propane dehydrogenation promoted by base metals

S Chen, Y Xu, X Chang, Y Pan, G Sun, X Wang, D Fu… - Science, 2024 - science.org
The industrial catalysts utilized for propane dehydrogenation (PDH) to propylene, an
important alternative to petroleum-based cracking processes, either use expensive metals or …

Design strategies of stable catalysts for propane dehydrogenation to propylene

ML Sun, ZP Hu, HY Wang, YJ Suo, ZY Yuan - ACS Catalysis, 2023 - ACS Publications
Propylene is one of the most important building blocks for the chemical industry. Traditional
propylene production, which is based on oil-based cracking processes, is being challenged …

Synergistic Interplay of Dual‐Active‐Sites on Metallic Ni‐MOFs Loaded with Pt for Thermal‐Photocatalytic Conversion of Atmospheric CO2 under Infrared Light …

W Ma, J Sun, S Yao, Y Wang, G Chen… - Angewandte Chemie …, 2023 - Wiley Online Library
Infrared light driven photocatalytic reduction of atmospheric CO2 is challenging due to the
ultralow concentration of CO2 (0.04%) and the low energy of infrared light. Herein, we …

Synergistic mechanism of sub‐nanometric ru clusters anchored on tungsten oxide nanowires for high‐efficient bifunctional hydrogen electrocatalysis

Y Pi, Z Qiu, Y Sun, H Ishii, YF Liao, X Zhang… - Advanced …, 2023 - Wiley Online Library
The construction of strong interactions and synergistic effects between small metal clusters
and supports offers a great opportunity to achieve high‐performance and cost‐effective …

Selective cleavage of chemical bonds in targeted intermediates for highly selective photooxidation of methane to methanol

C Han, Y Cao, W Yu, Z Huang, F Dong… - Journal of the …, 2023 - ACS Publications
Restrained by the uncontrollable cleavage process of chemical bonds in methane
molecules and corresponding formed intermediates, the target product in the reaction of …

Metastable gallium hydride mediates propane dehydrogenation on H2 co-feeding

G Sun, ZJ Zhao, L Li, C Pei, X Chang, S Chen… - Nature Chemistry, 2024 - nature.com
In heterogeneous catalysis, the catalytic dehydrogenation reactions of hydrocarbons often
exhibit a negative pressure dependence on hydrogen due to the competitive chemisorption …

CO2-mediated oxidative dehydrogenation of propane enabled by Pt-based bimetallic catalysts

P Zhai, Z **e, E Huang, DR Aireddy, H Yu, DA Cullen… - Chem, 2023 - cell.com
The greenhouse gas CO 2 is a promising soft oxidant for the oxidative dehydrogenation of
light alkanes. However, the occurrence of side reactions including cracking, hydrogenolysis …

Recent progress in catalytic dehydrogenation of propane over Pt-based catalysts

Y Shan, H Hu, X Fan, Z Zhao - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Light alkenes are the key building blocks in the chemical industry. As a propene on-purpose
production technology, propane dehydrogenation has drawn particular attention due to the …