Not only hydrogen bonds: Other noncovalent interactions

I Alkorta, J Elguero, A Frontera - Crystals, 2020 - mdpi.com
In this review, we provide a consistent description of noncovalent interactions, covering most
groups of the Periodic Table. Different types of bonds are discussed using their trivial …

Pnictogen bonding in coordination chemistry

KT Mahmudov, AV Gurbanov, VA Aliyeva… - Coordination Chemistry …, 2020 - Elsevier
The pnictogen bond (PnB) is a noncovalent attraction between electrophilic pnictogen
atoms, originated from the anisotropic distribution of electron density on Pn in a molecular …

Spodium bonds: noncovalent interactions involving group 12 elements

A Bauzá, I Alkorta, J Elguero… - Angewandte Chemie …, 2020 - Wiley Online Library
The term spodium (Sp) bond is proposed to refer to a net attractive interaction between any
element of Group 12 and electron‐rich atoms (Lewis bases or anions). These noncovalent …

Anion⋅⋅⋅ Anion Interactions Involving σ‐Holes of Perrhenate, Pertechnetate and Permanganate Anions

A Daolio, A Pizzi, G Terraneo, A Frontera… - …, 2021 - Wiley Online Library
In this communication experimental and theoretical results are reported affording strong
evidence that interactions between electron rich atoms and the metal of tetroxide anions of …

On the importance of σ–hole interactions in crystal structures

A Frontera, A Bauzá - Crystals, 2021 - mdpi.com
Elements from groups 14–18 and periods 3–6 commonly behave as Lewis acids, which are
involved in directional noncovalent interactions (NCI) with electron-rich species (lone pair …

On the importance of pnictogen and chalcogen bonding interactions in supramolecular catalysis

A Frontera, A Bauza - International Journal of Molecular Sciences, 2021 - mdpi.com
In this review, several examples of the application of pnictogen (Pn)(group 15) and
chalcogen (Ch) bonding (group 16) interactions in organocatalytic processes are gathered …

C (sp3) atoms as tetrel bond donors: A crystallographic survey

A Daolio, P Scilabra, G Terraneo, G Resnati - Coordination Chemistry …, 2020 - Elsevier
The σ-hole and π-hole interactions allow for a systematic understanding of some features of
the attractive interactions involving elements of groups 13–18 of the periodic table and of …

Noncovalent interactions involving group 6 in biological systems: The case of molybdopterin and Tungstopterin cofactors

A Bauzá, A Frontera - Chemistry–A European Journal, 2022 - Wiley Online Library
In this study we propose to coin the term Wolfium bond (WfB) to refer to a net attractive force
(noncovalent interaction) between any element of group 6 and electron donor atoms (neutral …

Anion recognition by neutral chalcogen bonding receptors: experimental and theoretical investigations

E Navarro‐García, B Galmés… - … A European Journal, 2020 - Wiley Online Library
The utilization of neutral receptors for the molecular recognition of anions based on
chalcogen bonding (ChB) is an undeveloped area of host‐guest chemistry. In this …