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Mesoionic and related less heteroatom-stabilized N-heterocyclic carbene complexes: synthesis, catalysis, and other applications
A Vivancos, C Segarra, M Albrecht - Chemical reviews, 2018 - ACS Publications
Mesoionic carbenes are a subclass of the family of N-heterocyclic carbenes that generally
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …
Beyond click chemistry–supramolecular interactions of 1, 2, 3-triazoles
B Schulze, US Schubert - Chemical Society Reviews, 2014 - pubs.rsc.org
The research on 1, 2, 3-triazoles has been lively and ever-growing since its stimulation by
the advent of click chemistry. The attractiveness of 1H-1, 2, 3-triazoles and their derivatives …
the advent of click chemistry. The attractiveness of 1H-1, 2, 3-triazoles and their derivatives …
Abnormal, mesoionic and remote N-heterocyclic carbene complexes
RH Crabtree - Coordination Chemistry Reviews, 2013 - Elsevier
Three different structural classes of NHC ligands can be distinguished: normal (nNHC),
abnormal (aNHC), alternatively called mesoionic (MIC), and remote (rNHC). General …
abnormal (aNHC), alternatively called mesoionic (MIC), and remote (rNHC). General …
Application of 1, 2, 3-triazolylidenes as versatile NHC-type ligands: synthesis, properties, and application in catalysis and beyond
KF Donnelly, A Petronilho, M Albrecht - Chemical Communications, 2013 - pubs.rsc.org
Triazolylidenes have rapidly emerged as a powerful subclass of N-heterocyclic carbene
ligands for transition metals. They are readily available through regioselective [2+ 3] …
ligands for transition metals. They are readily available through regioselective [2+ 3] …
Transition metal complexes of click-derived 1, 2, 3-triazoles as catalysts in various transformations: An overview and recent developments
The study of transition metal complexes linked with 1, 2, 3-triazoles has gained significant
attention due to their potential as effective catalysts in various chemical reactions. The 1, 2, 3 …
attention due to their potential as effective catalysts in various chemical reactions. The 1, 2, 3 …
Metal Complexes of Click‐Derived Triazoles and Mesoionic Carbenes: Electron Transfer, Photochemistry, Magnetic Bistability, and Catalysis
D Schweinfurth, L Hettmanczyk… - … für anorganische und …, 2017 - Wiley Online Library
Even though the existence of 1, 2, 3‐triazoles has been known for more than a century, the
recent discovery of a copper (I) catalyzed version of this reaction has attributed …
recent discovery of a copper (I) catalyzed version of this reaction has attributed …
A Heteroleptic Ferrous Complex with Mesoionic Bis (1, 2, 3‐triazol‐5‐ylidene) Ligands: Taming the MLCT Excited State of Iron (II)
Strongly σ‐donating N‐heterocyclic carbenes (NHCs) have revived research interest in the
catalytic chemistry of iron, and are now also starting to bring the photochemistry and …
catalytic chemistry of iron, and are now also starting to bring the photochemistry and …
Transfer hydrogenation of aldehydes and ketones in air with methanol and ethanol by an air-stable ruthenium–triazole complex
Coordination of 1, 4-disubstituted 1, 2, 3-triazoles L 1 and L 2 with [(p-cymene) RuCl2] 2
followed by dehydrochlorination in the presence of a base resulted in the formation of …
followed by dehydrochlorination in the presence of a base resulted in the formation of …
N-Heterocyclic carbene complexes enabling the α-arylation of carbonyl compounds
S Ostrowska, T Scattolin, SP Nolan - Chemical Communications, 2021 - pubs.rsc.org
The considerable importance of α-arylated carbonyl compounds, which are widely used as
final products or as key intermediates in the pharmaceutical industry, has prompted …
final products or as key intermediates in the pharmaceutical industry, has prompted …
PEPPSI‐Type Palladium Complexes Containing Basic 1, 2, 3‐Triazolylidene Ligands and Their Role in Suzuki–Miyaura Catalysis
D Canseco‐Gonzalez, A Gniewek… - … A European Journal, 2012 - Wiley Online Library
A series of PEPPSI‐type palladium (II) complexes was synthesized that contain 3‐
chloropyridine as an easily removable ligand and a triazolylidene as a strongly donating …
chloropyridine as an easily removable ligand and a triazolylidene as a strongly donating …