The strategies towards electrochemical generation of aryl radicals

X Zeng - Chemistry–A European Journal, 2024 - Wiley Online Library
The advancement in electrochemical techniques has unlocked a new path for achieving
unprecedented oxidations and reductions of aryl radical precursors in a controlled and …

Electrocatalytic generation of acyl radicals and their applications

H Zhang, S Liang, D Wei, K Xu… - European Journal of …, 2022 - Wiley Online Library
In this review, we highlighted the main achievements in the field of electrocatalytic
generation of acyl radicals and their applications. These electrochemical strategies were …

Selective fluorosulfonylation of thianthrenium salts enabled by electrochemistry

X Kong, Y Chen, Q Liu, WJ Wang, S Zhang… - Organic …, 2023 - ACS Publications
A practical electrochemically driven method for fluorosulfonylation of both aryl and alkyl
thianthrenium salts has been disclosed. The strategy does not need external redox reagents …

Direct electrochemical synthesis of arenesulfonyl fluorides from nitroarenes: a dramatic ionic liquid effect

X Kong, Q Liu, Y Chen, W Wang, HF Chen, W Wang… - Green …, 2024 - pubs.rsc.org
A practical electrochemical strategy for the direct synthesis of arenesulfonyl fluorides from
industrial feedstock nitroarenes is described. The key to success lies in using a cheap ionic …

Organomediated electrochemical fluorosulfonylation of aryl triflates via selective C–O bond cleavage

X Kong, Y Chen, X Chen, C Ma, M Chen… - Nature …, 2023 - nature.com
Although aryl triflates are essential building blocks in organic synthesis, the applications as
aryl radical precursors are limited. Herein, we report an organomediated electrochemical …

A facile synthesis route to BiPr composite nanosheets and sensitive electrochemical detection of L-cysteine

J Huang, F Tao, Z Sun, F Li, Z Cai, Y Zhang, C Fan… - Microchemical …, 2022 - Elsevier
The BiPr composite nanosheets have been synthesized by a facile hydrothermal method
using cetyltrimethyl ammonium bromide (CTAB). The BiPr composite products were …

Cobalt‐Catalyzed Deaminative Amino‐and Alkoxycarbonylation of Aryl Trialkylammonium Salts Promoted by Visible Light

AM Veatch, S Liu, EJ Alexanian - Angewandte Chemie, 2022 - Wiley Online Library
Catalytic carbonylations of aryl electrophiles via C (sp2)− N cleavage remains a significant
challenge. Herein, we demonstrate an aminocarbonylation of aniline‐derived …

Electrochemically Driven Denitrative Cyanation of Nitroarenes

Y Chen, Q Chen, S Zhang, K Feng, YQ Xu… - Organic …, 2024 - ACS Publications
A practical denitrative cyanation of feedstock nitroarenes under mild and transition metal-
free reaction conditions has been developed. The key to success lies in the use of …

Recent Advances in Electrochemical, Ni‐Catalyzed C− C Bond Formation

MC Franke, DJ Weix - Israel Journal of Chemistry, 2024 - Wiley Online Library
Nickel‐catalyzed cross‐electrophile coupling (XEC) is an efficient method to form carbon‐
carbon bonds and has become an important tool for building complex molecules. While XEC …

The triplet state of deprotonated mesoionic carbene Breslow intermediates is thermally accessible: Distal difunctionalization of aldehydes

Z Zhang, S Huang, CY Li, LL Zhao, W Liu, M Melaimi… - Chem Catalysis, 2022 - cell.com
Summary N-Heterocyclic carbene (NHC)-catalyzed transformations through electron-pair-
transfer processes have witnessed remarkable developments in the past decades …