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Frank–Kasper phases in block polymers
KD Dorfman - Macromolecules, 2021 - ACS Publications
The discovery of the Frank–Kasper σ phase in diblock copolymer and tetrablock terpolymer
melts catalyzed a renewed interest over the past decade in understanding particle-forming …
melts catalyzed a renewed interest over the past decade in understanding particle-forming …
Guidelines for superlattice engineering with giant molecules: The pivotal role of mesoatoms
Soft materials with nanostructures, such as Frank-Kasper (FK) and related spherical phases,
have garnered significant interest in recent years. However, there is still a lack of rational …
have garnered significant interest in recent years. However, there is still a lack of rational …
Expanding quasiperiodicity in soft matter: Supramolecular decagonal quasicrystals by binary giant molecule blends
The quasiperiodic structures in metal alloys have been known to depend on the existence of
icosahedral order in the melt. Among different phases observed in intermetallics, decagonal …
icosahedral order in the melt. Among different phases observed in intermetallics, decagonal …
Precisely encoding geometric features into discrete linear polymer chains for robust structural engineering
Molecular shape is an essential parameter that regulates the self-organization and
recognition process, which has not yet been well appreciated and exploited in block …
recognition process, which has not yet been well appreciated and exploited in block …
Complex phase behavior in particle-forming AB/AB′ diblock copolymer blends with variable core block lengths
Over the past decade, a wealth of complexity has been reported in the packing of
compositionally asymmetric, particle-forming diblock copolymer melts, beginning with the …
compositionally asymmetric, particle-forming diblock copolymer melts, beginning with the …
Tuning the Complex Spherical Phase of Sugar-Based Block Co-Oligomer via Single-Monomer-Mediated Composition Variation
WC Chiu, YH Cheng, JH Lin, CH Tung… - …, 2024 - ACS Publications
We show that a full spectrum of Frank–Kasper (FK) phase and dodecagonal quasicrystal
(DDQC) having been discovered among different block copolymers (BCPs) can be …
(DDQC) having been discovered among different block copolymers (BCPs) can be …
Phase behavior of linear-bottlebrush block polymers
Block copolymers (BCPs) self-assembled into 3D network phases are promising for
designing useful materials with multiple properties that rely on domain continuity. However …
designing useful materials with multiple properties that rely on domain continuity. However …
Mesoatomic Engineering for Programmable Spherical Packing Superlattices in Self-Assembly of Giant Molecular Clusters
In the realm of soft matter, the self-assembly of giant molecules into predefined spherical
packing superlattices offers a promising avenue for creating materials with specific …
packing superlattices offers a promising avenue for creating materials with specific …
Enhancing ion transport in charged block copolymers by stabilizing low symmetry morphology: Electrostatic control of interfaces
Recently, the interest in charged polymers has been rapidly growing due to their uses in
energy storage and transfer devices. Yet, polymer electrolyte-based devices are not on the …
energy storage and transfer devices. Yet, polymer electrolyte-based devices are not on the …
Unwinding Spherical Helices Increases Entropy and Stability of Frank–Kasper and Body-Centered-Cubic Periodic Arrays To Facilitate Discrimination between Self …
Spherical supramolecular dendrimers including helical, self-organize soft Frank–Kasper,
other cubic such as body-centered cubic, and quasicrystal periodic and quasiperiodic …
other cubic such as body-centered cubic, and quasicrystal periodic and quasiperiodic …