Catalytic strategies and mechanism analysis orbiting the center of critical intermediates in lignin depolymerization

C Zhang, X Shen, Y **, J Cheng, C Cai… - Chemical …, 2023 - ACS Publications
Lignin, as a precious resource given to mankind by nature with abundant functional aromatic
structures, has drawn much attention in the recent decade from academia to industry …

Review of old chemistry and new catalytic advances in the on-purpose synthesis of butadiene

EV Makshina, M Dusselier, W Janssens… - Chemical Society …, 2014 - pubs.rsc.org
Increasing demand for renewable feedstock-based chemicals is driving the interest of both
academic and industrial research to substitute petrochemicals with renewable chemicals …

Hydrodeoxygenation of potential platform chemicals derived from biomass to fuels and chemicals

K Tomishige, M Yabushita, J Cao, Y Nakagawa - Green Chemistry, 2022 - pubs.rsc.org
Biomass valorization has emerged as a promising and sustainable means of
accommodating value-added chemicals. To produce such chemicals, various transformation …

Homogeneous catalysis for the production of low-volume, high-value chemicals from biomass

TA Bender, JA Dabrowski, MR Gagné - Nature Reviews Chemistry, 2018 - nature.com
The transition from petroleum to biorenewable sources of carbon to meet our energy and
chemical feedstock needs is difficult, in part because these sources are so different, with …

[PDF][PDF] Deoxygenation of Biomass‐Derived Feedstocks: Oxorhenium‐Catalyzed Deoxydehydration of Sugars and Sugar Alcohols

M Shiramizu, FD Toste - Angewandte Chemie-International …, 2012 - researchgate.net
The conversion of renewable cellulosic biomass into fuels and chemicals has attracted
increased attention with the growing demand for sustainability.[1] However, one …

Hydrodeoxygenation of vicinal OH groups over heterogeneous rhenium catalyst promoted by palladium and ceria support

N Ota, M Tamura, Y Nakagawa, K Okumura… - Angewandte …, 2015 - Wiley Online Library
Abstract Heterogeneous ReOx–Pd/CeO2 catalyst showed excellent performance for
simultaneous hydrodeoxygenation of vicinal OH groups. High yield (> 99%), turnover …

Expanding the Scope of Biomass‐Derived Chemicals through Tandem Reactions Based on Oxorhenium‐Catalyzed Deoxydehydration

M Shiramizu, FD Toste - Angewandte Chemie International …, 2013 - Wiley Online Library
With the growing demand for sustainability, cellulosic biomass has attracted much attention
as a renewable, carbonneutral and inexpensive feedstock for chemicals and fuels. However …

Performance, Structure, and Mechanism of ReOx–Pd/CeO2 Catalyst for Simultaneous Removal of Vicinal OH Groups with H2

N Ota, M Tamura, Y Nakagawa, K Okumura… - ACS …, 2016 - ACS Publications
The ceria-supported rhenium catalyst modified with palladium (ReO x–Pd/CeO2 (Re= 2
wt%, Pd/Re= 0.25)) is still the best catalyst for simultaneous hydrodeoxygenation. Higher Re …

Deoxydehydration with molecular hydrogen over ceria-supported rhenium catalyst with gold promoter

S Tazawa, N Ota, M Tamura, Y Nakagawa… - ACS …, 2016 - ACS Publications
Gold nanoparticle cocatalyst and ceria support catalyst enabled the use of H2 as a reductant
for Re-catalyzed deoxydehydration (DODH), converting vicinal diols to olefins with higher …

Rhenium-catalyzed dehydration and deoxydehydration of alcohols and polyols: opportunities for the formation of olefins from biomass

S Raju, ME Moret, RJM Klein Gebbink - ACS Catalysis, 2015 - ACS Publications
In view of the depletion of petroleum oils, new synthetic routes for the sustainable production
of chemicals, fuels, and energy from renewable biomass sources are currently widely …