Retracted Article: Noncovalently bound excited-state dimers: a perspective on current time-dependent density functional theory approaches applied to aromatic …

AC Hancock, L Goerigk - RSC advances, 2022 - pubs.rsc.org
Excimers are supramolecular systems whose binding strength is influenced by many factors
that are ongoing challenges for computational methods, such as charge transfer, exciton …

Accuracy of TD-DFT geometries: a fresh look

E Bremond, M Savarese, C Adamo… - Journal of chemical …, 2018 - ACS Publications
We benchmark a panel of 48 DFT exchange–correlation functionals in the framework of TD-
DFT optimizations of the geometry of valence singlet excited states. To this end, we use a set …

Probing the delicate balance between pauli repulsion and London dispersion with triphenylmethyl derivatives

S Rösel, J Becker, WD Allen… - Journal of the American …, 2018 - ACS Publications
The long-known, ubiquitously present, and always attractive London dispersion (LD)
interaction was probed with hexaphenylethane (HPE) derivatives. A series of all-meta …

Suppressing dimer formation by increasing conformational freedom in multi-carbazole thermally activated delayed fluorescence emitters

L Salah, MK Etherington, A Shuaib, A Danos… - Journal of Materials …, 2021 - pubs.rsc.org
Ideal emitters for organic light-emitting diodes (OLEDs) are capable of efficiently harvesting
non-emissive triplet states, have high colour stabilities, and possess high …

Bright Luminescence by Combining Chiral [2.2] Paracyclophane with a Boron–Nitrogen‐Doped Polyaromatic Hydrocarbon Building Block

MR Rapp, W Leis, F Zinna, L Di Bari… - … A European Journal, 2022 - Wiley Online Library
Novel BN‐doped compounds based on chiral, tetrasubstituted [2.2] paracyclophane and
NBN‐benzo [f, g] tetracene were synthesized by Sonogashira–Hagihara coupling …

A thorough understanding of the nonlinear optical properties of BODIPY/carborane/diketopyrrolopyrrole hybrid chromophores: module contribution, linear combination …

HQ Wang, JT Ye, Y Zhang, YY Zhao… - Journal of Materials …, 2019 - pubs.rsc.org
In an attempt to enrich the understanding of essential structure–nonlinear optical (NLO)
property correlations in multi-component photoactive boron dipyrromethene/closo …

Menthol and fatty acid-based hydrophobic deep eutectic solvents as media for enzyme activation

AAM Elgharbawy, SS Syed Putra, HW Khan, NAN Azmi… - Processes, 2023 - mdpi.com
This research aims to provide insights into the biological efficacy of a newly formed
hydrophobic deep eutectic solvent (DES). A DES based on menthol was successfully …

Dispersion Interactions in Exciton-Localized States. Theory and Applications to π–π* and n− π* Excited States

MR Jangrouei, A Krzemińska, M Hapka… - Journal of Chemical …, 2022 - ACS Publications
We address the problem of intermolecular interaction energy calculations in molecular
complexes with localized excitons. Our focus is on the correct representation of the …

Theoretical study of the excitation of proflavine H-dimers in an aqueous solution: the effect of functionals and dispersion corrections

ES Savenko, VV Kostjukov - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Analysis of the ground and excited states of the H-dimer of the proflavine dye cation (PF) in
an aqueous solution was performed using the DFT/TD-DFT method with an implicit …

London Dispersion Effects on the Stability of Heavy Tetrel Molecules

KL Mears, PP Power - Chemistry–A European Journal, 2023 - Wiley Online Library
London dispersion (LD) interactions, which stem from long‐range electron correlations
arising from instantaneously induced dipoles can occur between neighboring atoms or …