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[HTML][HTML] Structural analysis of spin-crossover materials: From molecules to materials
E Collet, P Guionneau - Comptes Rendus Chimie, 2018 - Elsevier
In molecular spin-crossover materials, the spin-state switching is strongly coupled with
changes in the structural degrees of freedom, which play a central role in the alteration of …
changes in the structural degrees of freedom, which play a central role in the alteration of …
OctaDist: a tool for calculating distortion parameters in spin crossover and coordination complexes
OctaDist is an interactive and visual program for determination of structural distortion in
octahedral coordination complexes such as spin crossover complexes, single-ion magnets …
octahedral coordination complexes such as spin crossover complexes, single-ion magnets …
A critical review of the T (LIESST) temperature in spin crossover materials− What it is and what it is not
G Chastanet, C Desplanches, C Baldé, P Rosa… - Chemistry …, 2018 - hal.science
Light-Induced Excited Spin-State Trap** has been studied since 1982 in solution and
1984 in solid state as it offers a reversible way of photoswitching the electronic configuration …
1984 in solid state as it offers a reversible way of photoswitching the electronic configuration …
Crystallography and spin-crossover. A view of breathing materials
P Guionneau - Dalton Transactions, 2014 - pubs.rsc.org
The spin-crossover phenomenon (SCO) is a fascinating field that potentially concerns any
material containing a (d4–d7) transition metal complex finding therefore an echo in as …
material containing a (d4–d7) transition metal complex finding therefore an echo in as …
Sequential activation of molecular breathing and bending during spin-crossover photoswitching revealed by femtosecond optical and X-ray absorption spectroscopy
We study the basic mechanisms allowing light to photoswitch at the molecular scale a spin-
crossover material from a low-to a high-spin state. Combined femtosecond x-ray absorption …
crossover material from a low-to a high-spin state. Combined femtosecond x-ray absorption …
Enlightening the alkali ion role in the photomagnetic effect of FeCo Prussian Blue analogues
FeCo Prussian blue analogues of general formula A x Co y [Fe (CN) 6] z are responsive,
non-stoichiometric materials whose magnetic and optical properties can be reversibly …
non-stoichiometric materials whose magnetic and optical properties can be reversibly …
First Step Towards a Devil's Staircase in Spin‐Crossover Materials
E Trzop, D Zhang, L Piñeiro‐Lopez… - Angewandte …, 2016 - Wiley Online Library
The unprecedented bimetallic 2D coordination polymer {Fe [(Hg (SCN) 3) 2](4, 4′‐bipy) 2}
n exhibits a thermal high‐spin (HS)↔ low‐spin (LS) staircase‐like conversion characterized …
n exhibits a thermal high‐spin (HS)↔ low‐spin (LS) staircase‐like conversion characterized …
[HTML][HTML] Light-induced spin crossover—Solution and solid-state processes
This article overviews the different light-induced spin-crossover processes that are induced
using ligand photoreaction, photothermal effects, or optical absorption of the center metallic …
using ligand photoreaction, photothermal effects, or optical absorption of the center metallic …
Relationship between the molecular structure and switching temperature in a library of spin-crossover molecular materials
Structure–function relationships relating the spin-crossover (SCO) midpoint temperature (T
1/2) in the solid state are surveyed for 43 members of the iron (II) dipyrazolylpyridine family …
1/2) in the solid state are surveyed for 43 members of the iron (II) dipyrazolylpyridine family …
Ultrafast Light-Induced Spin-State Trap** Photophysics Investigated in Fe(phen)2(NCS)2 Spin-Crossover Crystal
Conspectus Few photoactive molecules undergo a complete transformation of physical
properties (magnetism, optical absorption, etc.) when irradiated with light. Such phenomena …
properties (magnetism, optical absorption, etc.) when irradiated with light. Such phenomena …