Construction of hierarchically chiral metal–organic frameworks for fast and mild asymmetric catalysis

Z Sharifzadeh, SAA Razavi, A Morsali - Green Chemistry, 2023‏ - pubs.rsc.org
The production of hierarchically porous metal–organic frameworks (HP-MOFs) while
retaining their crystallinity utilizing the mixed-linker approach is still challenging due to the …

Imine-and amine-type macrocycles derived from chiral diamines and aromatic dialdehydes

J Lisowski - Molecules, 2022‏ - mdpi.com
The condensation of aromatic dialdehydes with chiral diamines, such as 1, 2-trans-
diaminocyclohexane, leads to various enantiopure or meso-type macrocyclic Schiff bases …

Photothermal conversion triggered thermal asymmetric catalysis within metal nanoparticles loaded homochiral covalent organic framework

HC Ma, CC Zhao, GJ Chen, YB Dong - Nature Communications, 2019‏ - nature.com
For seeking high enantiopurity, the previously reported thermal asymmetric catalysis is
usually carried out at low temperature sometimes with limited yield, that is, the high …

Recent progress in copper catalyzed asymmetric Henry reaction

S Zhang, Y Li, Y Xu, Z Wang - Chinese Chemical Letters, 2018‏ - Elsevier
Henry reaction is one of the most classical reactions to construct synthetically useful product
nitro alcohol, which as a privileged skeleton is widely distributed in various pharmaceuticals …

Direct Catalytic Synthesis of Unprotected 2‐Amino‐1‐Phenylethanols from Alkenes by Using Iron (II) Phthalocyanine

L Legnani, B Morandi - Angewandte Chemie International …, 2016‏ - Wiley Online Library
Aryl‐substituted amino alcohols are privileged scaffolds in medicinal chemistry and natural
products. Herein, we report that an exceptionally simple and inexpensive FeII complex …

Defect engineering enables synergistic action of hierarchical porosity and multifunctionality for efficient catalysis of diverse reactions

Z Sharifzadeh, A Morsali - Applied Materials Today, 2023‏ - Elsevier
The limitations of embedding suitable functional groups as Brønsted and Lewis pairs in
metal–organic materials hinder their application especially to promote catalysis reactions …

Enhanced activity and enantioselectivity of henry reaction by the postsynthetic reduction modification for a chiral Cu (salen)-based metal–organic framework

Y Fan, Y Ren, J Li, C Yue, H Jiang - Inorganic chemistry, 2018‏ - ACS Publications
Metal–organic frameworks (MOFs) imbedded privileged molecular catalysts are of particular
interest due to their higher catalytic activities derived from the MOFs pore/channel …

DFT stimulation and experimental insights of chiral Cu (ii)–salen scaffold within the pocket of MWW-zeolite and its catalytic study

P Lakhani, D Chodvadiya, PK Jha, VK Gupta… - Physical Chemistry …, 2023‏ - pubs.rsc.org
A Cu (II)–salen complex encapsulated in MWW-framework as an efficient chiral
organocatalyst was developed for the synthesis of 3, 4-dihydropyrimidin-2-(1H)-one …

Synthesis, antimicrobial, DFT, and in silico pharmacokinetic profiling of nitroaldol quinoline derivatives: A comprehensive exploration for designing potential oral …

F Guenfoud, O Khaoua, Z Cherak, L Loucif… - Journal of Molecular …, 2024‏ - Elsevier
This study presents a thorough exploration of the synthesis, biological activities, and
molecular properties of a novel series of β-nitroaldol quinoline derivatives (4a-4i). Structural …

Enantiospecific Photoresponsive Metallacages Based on Sterically Hindered Diarylethenes for Chiral Recognition

S Guo, M Li, C Lian, W Zhang, H Hu, N Lv… - CCS …, 2024‏ - chinesechemsoc.org
Dynamic chiral materials with noncontactable, light-activated, and reversible features have
attracted considerable attention in photoprogrammable liquid crystals and chiral …