Two-dimensional metal-organic framework materials: synthesis, structures, properties and applications

G Chakraborty, IH Park, R Medishetty… - Chemical Reviews, 2021 - ACS Publications
Among the recent developments in metal-organic frameworks (MOFs), porous layered
coordination polymers (CPs) have garnered attention due to their modular nature and …

Emerging trends in spin crossover (SCO) based functional materials and devices

KS Kumar, M Ruben - Coordination Chemistry Reviews, 2017 - Elsevier
The design and synthesis of functional molecules with controllable properties are at the
forefront of modern materials chemistry research due to their diverse applicability, especially …

Spin crossover with thermal hysteresis: practicalities and lessons learnt

S Brooker - Chemical Society Reviews, 2015 - pubs.rsc.org
The observation of spin crossover with thermal hysteresis loops of more than a few Kelvin
remains relatively uncommon and unpredictable, so is a relatively underdeveloped, but …

Symmetry-breaking structural phase transitions in spin crossover complexes

M Shatruk, H Phan, BA Chrisostomo… - Coordination Chemistry …, 2015 - Elsevier
We review spin-crossover (SCO) complexes of 3d transition metal ions that exhibit structural
phase transitions (SPTs) associated with changes in the space group symmetry. An analysis …

Molecular magnetic materials: concepts and applications

B Sieklucka, D Pinkowicz - 2017 - books.google.com
A comprehensive overview of this rapidly expanding interdisciplinary field of research. After
a short introduction to the basics of magnetism and molecular magnetism, the text goes on to …

Crystalline central-metal transformation in metal-organic frameworks

H Wang, W Meng, J Wu, J Ding, H Hou… - Coordination Chemistry …, 2016 - Elsevier
Recently, there has been considerable interest in the transformation of metal nodes in metal-
organic frameworks (MOFs) because this transformation can yield favorable changes in their …

Hysteretic Four‐Step Spin Crossover within a Three‐Dimensional Porous Hofmann‐like Material

JE Clements, JR Price, SM Neville… - Angewandte …, 2016 - Wiley Online Library
Materials that display multiple stepped spin crossover (SCO) transitions with accompanying
hysteresis present the opportunity for ternary, quaternary, and quinary electronic switching …

[HTML][HTML] Pressure effect investigations on spin-crossover coordination compounds

AB Gaspar, G Molnár, A Rotaru, HJ Shepherd - Comptes Rendus Chimie, 2018 - Elsevier
The piezochromic properties of spin-crossover complexes have been recognized for a long
time, with increasing pressure favouring the low spin state due to its smaller volume and …

Spin crossover in iron (II) complexes of 3, 4, 5-tri-substituted-1, 2, 4-triazole (Rdpt), 3, 5-di-substituted-1, 2, 4-triazolate (dpt−), and related ligands

HLC Feltham, AS Barltrop, S Brooker - Coordination Chemistry Reviews, 2017 - Elsevier
A general introduction to spin crossover involving iron (II) is provided. Then the 26 examples
of 3, 4, 5-tri-substituted-1, 2, 4-triazole (mostly Rdpt and Rppt) ligands and the 11 examples …

First Step Towards a Devil's Staircase in Spin‐Crossover Materials

E Trzop, D Zhang, L Piñeiro‐Lopez… - Angewandte …, 2016 - Wiley Online Library
The unprecedented bimetallic 2D coordination polymer {Fe [(Hg (SCN) 3) 2](4, 4′‐bipy) 2}
n exhibits a thermal high‐spin (HS)↔ low‐spin (LS) staircase‐like conversion characterized …