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Coordination and organometallic chemistry of metal− NO complexes
TW Hayton, P Legzdins, WB Sharp - Chemical Reviews, 2002 - ACS Publications
The chemistry of transition-metal-NO complexes, or metal nitrosyls, has taken on added
significance in recent years because of the important role that nitric oxide has been found to …
significance in recent years because of the important role that nitric oxide has been found to …
Hydride Fluxionality in Transiton Metal Complexes: An Approach to the Understanding of Mechanistic Features and Structural Diversities
DG Gusev, H Berke - Chemische Berichte, 1996 - Wiley Online Library
The mechanisms of intramolecular dynamics in transition metal hydride complexes are
surveyed in this review. The NMR data for a number of fluxional hydrides are interpreted in …
surveyed in this review. The NMR data for a number of fluxional hydrides are interpreted in …
Spectroscopic Evidence for Intermolecular M−H···H−OR Hydrogen Bonding: Interaction of WH(CO)2(NO)L2 Hydrides with Acidic Alcohols
ES Shubina, NV Belkova, AN Krylov… - Journal of the …, 1996 - ACS Publications
Intermolecular hydrogen bonding of acidic alcohols (PhOH,(CF3) 2CHOH (HFIP),(CF3)
3CHOH (PFTB)) to the hydride ligand of WH (CO) 2 (NO) L2 (L= PMe3 (1), PEt3 (2), P (OiPr) …
3CHOH (PFTB)) to the hydride ligand of WH (CO) 2 (NO) L2 (L= PMe3 (1), PEt3 (2), P (OiPr) …
Reaction monitoring using SABRE-hyperpolarized benchtop (1 T) NMR spectroscopy
O Semenova, PM Richardson, AJ Parrott… - Analytical …, 2019 - ACS Publications
The conversion of [IrCl (COD)(IMes)](COD= cis, cis-1, 5-cyclooctadiene, IMes= 1, 3-bis (2, 4,
6-trimethyl-phenyl) imidazole-2-ylidene) in the presence of an excess of para-hydrogen (p …
6-trimethyl-phenyl) imidazole-2-ylidene) in the presence of an excess of para-hydrogen (p …
Nature of the bonding in metal-silane σ-complexes
GS McGrady, P Sirsch, NP Chatterton… - Inorganic …, 2009 - ACS Publications
The nature of metal silane σ-bond interaction has been investigated in several key systems
by a range of experimental and computational techniques. The structure of [Cp′ Mn (CO) 2 …
by a range of experimental and computational techniques. The structure of [Cp′ Mn (CO) 2 …
Molecular hydrogen tweezers: Structure and mechanisms by neutron diffraction, NMR, and deuterium labeling studies in solid and solution
F Schulz, V Sumerin, S Heikkinen… - Journal of the …, 2011 - ACS Publications
The mechanism of reversible hydrogen activation by ansa-aminoboranes, 1-N-TMPH-CH2-2-
[HB (C6F5) 2] C6H4 (NHHB), was studied by neutron diffraction and thermogravimetric mass …
[HB (C6F5) 2] C6H4 (NHHB), was studied by neutron diffraction and thermogravimetric mass …
Synthesis, Structural Diversity, Dynamics, and Acidity of the M(II) and M(IV) Complexes [MH3(PR3)4]+ (M = Fe, Ru, Os; R = Me, Et)
DG Gusev, R Hübener, P Burger… - Journal of the …, 1997 - ACS Publications
The syntheses of complexes MH2L4 and their protonated analogues [MH3L4]+(M= Fe (1),
Ru (2), Os (3); R= Me (a), Et (b)) are described. The structures of 1a, 1b, and 3a were …
Ru (2), Os (3); R= Me (a), Et (b)) are described. The structures of 1a, 1b, and 3a were …
Structure and H2-Loss Energies of OsHX (H2)(CO) L2 Complexes (L= P (t-Bu) 2Me, P (i-Pr) 3; X= Cl, I, H): Attempted Correlation of 1 J (H− D), T 1min, and Δ G⧧
DG Gusev, RL Kuhlman, KB Renkema… - Inorganic …, 1996 - ACS Publications
1 J (H− D), T 1min and k 1 for H2 dissociation from OsHX (H2)(CO) L2 have been measured
for X= Cl, I, H (L= P (t-Bu) 2Me or P (i-Pr) 3), as well as for OsCl2 (H2)(CO)(P (i-Pr) 3) 2. For …
for X= Cl, I, H (L= P (t-Bu) 2Me or P (i-Pr) 3), as well as for OsCl2 (H2)(CO)(P (i-Pr) 3) 2. For …
[BUCH][B] NMR spectroscopy in liquids and solids
VI Bakhmutov - 2015 - api.taylorfrancis.com
This book is intended for those who are just beginning research activity in chemistry,
biochemistry, geochemistry, chemical engineering, or other science and wish to use NMR as …
biochemistry, geochemistry, chemical engineering, or other science and wish to use NMR as …
[HTML][HTML] Disentangling different modes of mobility for triphenylphosphine oxide adsorbed on alumina
PJ Hubbard, JW Benzie, VI Bakhmutov… - The Journal of Chemical …, 2020 - pubs.aip.org
Triphenylphosphine oxide (TPPO, 1) has been adsorbed on neutral alumina by dry grinding
of the components in the absence of a solvent. The adsorption proves translational mobility …
of the components in the absence of a solvent. The adsorption proves translational mobility …