Mining for Metal–Organic Systems: Chemistry Frontiers of Th-, U-, and Zr-Materials

KC Park, J Lim, GC Thaggard… - Journal of the American …, 2024 - ACS Publications
The conceptual framework presented in this Perspective overviews the design principles of
innovative thorium-based materials that could address urgent needs of the medicinal …

Amino-functionalized MOF-on-MOF architectural nanocomplexes composed for radioactive-iodine efficient adsorption

L Liu, L Chen, K Thummavichai, Z Ye, Y Wang… - Chemical Engineering …, 2023 - Elsevier
The effective capture of radioactive iodine vapor is crucial for radiation safety during spent
fuel reprocessing. However, current materials used for iodine vapor capture have limitations …

Adsorption and Detection of Iodine Species by a Thorium-Based Metal–Organic Framework

Y Ju, ZJ Li, J Qiu, X Li, J Yang, ZH Zhang… - Inorganic …, 2023 - ACS Publications
Actinide-bearing metal–organic frameworks (MOFs) encompass intriguing structures and
properties, but the radioactivity of actinide cripples their applications. Herein, we have …

Efficient iodine uptake of ultra thermally stable conjugated copolymers bearing biaceanthrylenyl moieties and contorted aromatic units using a [3+ 2] palladium …

N Baig, S Shetty, R Bargakshatriya, SK Pramanik… - ACS …, 2023 - ACS Publications
A novel series of copolymers made from alternating aromatic surrogates with contorted and
spiro compounds, denoted as BCP1–3, was successfully synthesized employing a …

Promising CO2 Capture and Effective Iodine Adsorption of Hyper-Cross-Linked Conjugated Porous Organic Polymers Prepared from a Cyclopentannulation Reaction

N Baig, S Shetty, S Abdul Wahed… - … Applied Materials & …, 2024 - ACS Publications
Three novel conjugated porous organic polymers, denoted as C-POP1–3 and which consist
of alternating pyrene cores with various contorted fluorene surrogates, were successfully …

Synthesis and iodine adsorption properties of organometallic copolymers with propeller-shaped Fe (II) clathrochelates bridged by different diaryl thioether and their …

S Shetty, N Baig, B Alameddine - Polymers, 2022 - mdpi.com
Three organometallic copolymers, ICP1-3, containing iron (II) clathrochelate units with
cyclohexyl lateral groups and interconnected by various thioether derivatives were …

Influence of Interfering Ions and Adsorption Temperature on Radioactive Iodine Removal Efficiency and Stability of Ni-MOF-74 and Zr-UiO-66

T Alghamdi, PO Aina, AA Rownaghi… - ACS applied materials & …, 2023 - ACS Publications
Metal–organic frameworks (MOFs) often exhibit an exceptional adsorption-based separation
performance for a variety of gases, ions, and liquids. While most radioactive iodine removal …

Synthesis of iron (II) clathrochelate-based Poly (vinylene sulfide) with tetraphenylbenzene bridging units and their selective oxidation into their corresponding poly …

N Baig, S Shetty, SS Habib, AA Husain, S Al-Mousawi… - Polymers, 2022 - mdpi.com
The development of a simple and efficient synthetic methodology to engineer functional
polymer materials for gas adsorption is necessary due to its relevance for various …

Iodine and nickel ions adsorption by conjugated copolymers bearing repeating units of dicyclopentapyrenyl and various thiophene derivatives

S Shetty, N Baig, SA Wahed, A Hassan, N Das… - Polymers, 2023 - mdpi.com
The synthesis of three conjugated copolymers TPP1–3 was carried out using a palladium-
catalyzed [3+ 2] cycloaddition polymerization of 1, 6-dibromopyrene with various dialkynyl …

Selective Carbon Dioxide Capture and Ultrahigh Iodine Uptake by Tetraphenylethylene-Functionalized Nitrogen-Rich Porous Organic Polymers

S Sen, R Diab, MH Al-Sayah, R Jabbour… - ACS Applied Polymer …, 2024 - ACS Publications
The development of efficient adsorbent materials capable of dual capture of carbon dioxide
(CO2) and iodine is of great importance due to the significant contribution of anthropogenic …