Formazanate coordination compounds: synthesis, reactivity, and applications

JB Gilroy, E Otten - Chemical Society Reviews, 2020 - pubs.rsc.org
Formazans (Ar1-NH-NCR3-NN-Ar5), a class of nitrogen-rich and highly colored compounds,
have been known since the late 1800s and studied more closely since the early 1940s …

Photostable small-molecule NIR-II fluorescent scaffolds that cross the blood–brain barrier for noninvasive brain imaging

S Wang, H Shi, L Wang, A Loredo… - Journal of the …, 2022 - ACS Publications
The second near-infrared (NIR-II, 1000–1700 nm) fluorescent probes have significant
advantages over visible or NIR-I (600–900 nm) imaging for both depth of penetration and …

The coordination potential of indigo, anthraquinone and related redox-active dyes

W Kaim, GK Lahiri - Coordination Chemistry Reviews, 2019 - Elsevier
The chromophores of several classes of well-established dyes, eg, indigo, 9, 10-
anthraquinones, formazanes, diketopyrrolopyrroles (DPPs), or certain azo compounds, are …

Near‐infrared photoluminescence and electrochemiluminescence from a remarkably simple boron difluoride formazanate dye

RR Maar, R Zhang, DG Stephens… - Angewandte Chemie …, 2019 - Wiley Online Library
A boron difluoride formazanate dye that exhibits near‐infrared photoluminescence and
electrochemiluminescence was produced via a straightforward two‐step synthesis …

Rigid π-extended boron difluoride complex with mega-stokes shift for bioimaging

M Más-Montoya, MF Montenegro… - Organic …, 2020 - ACS Publications
The rational design of a rigid π-extended ligand, suitable for the formation of four-coordinate
boron complexes, has led to the synthesis of the fused hexacyclic structure of carbazolo [2, 1 …

Widening the window of spin-crossover temperatures in bis (formazanate) iron (II) complexes via steric and noncovalent interactions

F Milocco, F de Vries, HS Siebe, S Engbers… - Inorganic …, 2021 - ACS Publications
Bis (formazanate) iron (II) complexes undergo a thermally induced S= 0 to S= 2 spin
transition in solution. Here we present a study of how steric effects and π-stacking …

Accurate electronic and optical properties of organic doublet radicals using machine learned range-separated functionals

CW Ju, Y Shen, EJ French, J Yi, H Bi… - The Journal of …, 2024 - ACS Publications
Luminescent organic semiconducting doublet-spin radicals are unique and emergent optical
materials because their fluorescent quantum yields (Φfl) are not compromised by the spin …

WORM type memory device based on ionic organotin complex using 1, 5-diphenyl-3-(2-pyridyl) formazan ligand

S Birara, A Betal, P Lama, S Sahu, RK Metre - Journal of Molecular …, 2023 - Elsevier
Synthesis, structure, and write once read many (WORM) type memory behavior of an ionic
organotin complex containing a 2-pyridine substituted formazan ligand is described herein …

The photoinactivation of pathogenic bacteria using synthesized benzodioxole-BODIPY dyes

N Tursynova, IH Maliszewska, K Jóźwiak… - … of Photochemistry and …, 2024 - Elsevier
The paper focuses on the synthesis of the chloro-, methyl and carbonyl derivatives of
Benzodioxole-BODIPY dye (BODIPY–4, 4-difluoro-4-bora-3a, 4a-diaza-s-indacene). Three …

π-Conjugated copolymers composed of boron formazanate and their application for a wavelength converter to near-infrared light

Y Kawano, Y Ito, S Ito, K Tanaka, Y Chujo - Macromolecules, 2021 - ACS Publications
We report conjugated polymers consisting of boron formazanate in the main chains. By
employing typical donor-type comonomers, such as fluorene and bithiophene, copolymers …