Nuclear quantum effects in water and aqueous systems: Experiment, theory, and current challenges

M Ceriotti, W Fang, PG Kusalik, RH McKenzie… - Chemical …, 2016 - ACS Publications
Nuclear quantum effects influence the structure and dynamics of hydrogen-bonded systems,
such as water, which impacts their observed properties with widely varying magnitudes. This …

Self-diffusion coefficient of bulk and confined water: a critical review of classical molecular simulation studies

IN Tsimpanogiannis, OA Moultos, LFM Franco… - Molecular …, 2019 - Taylor & Francis
We present a detailed overview of classical molecular simulation studies examining the self-
diffusion coefficient of water. The self-diffusion coefficient is directly associated with the …

[HTML][HTML] CP2K: An electronic structure and molecular dynamics software package-Quickstep: Efficient and accurate electronic structure calculations

TD Kühne, M Iannuzzi, M Del Ben, VV Rybkin… - The Journal of …, 2020 - pubs.aip.org
CP2K is an open source electronic structure and molecular dynamics software package to
perform atomistic simulations of solid-state, liquid, molecular, and biological systems. It is …

[HTML][HTML] Perspective: How good is DFT for water?

MJ Gillan, D Alfe, A Michaelides - The Journal of chemical physics, 2016 - pubs.aip.org
Kohn-Sham density functional theory (DFT) has become established as an indispensable
tool for investigating aqueous systems of all kinds, including those important in chemistry …

Ab initio theory and modeling of water

M Chen, HY Ko, RC Remsing… - Proceedings of the …, 2017 - National Acad Sciences
Water is of the utmost importance for life and technology. However, a genuinely predictive
ab initio model of water has eluded scientists. We demonstrate that a fully ab initio approach …

How van der Waals interactions determine the unique properties of water

T Morawietz, A Singraber… - Proceedings of the …, 2016 - National Acad Sciences
Whereas the interactions between water molecules are dominated by strongly directional
hydrogen bonds (HBs), it was recently proposed that relatively weak, isotropic van der …

Quantum dynamics and spectroscopy of ab initio liquid water: The interplay of nuclear and electronic quantum effects

O Marsalek, TE Markland - The journal of physical chemistry …, 2017 - ACS Publications
Understanding the reactivity and spectroscopy of aqueous solutions at the atomistic level is
crucial for the elucidation and design of chemical processes. However, the simulation of …

Neural network molecular dynamics simulations of solid–liquid interfaces: water at low-index copper surfaces

SK Natarajan, J Behler - Physical Chemistry Chemical Physics, 2016 - pubs.rsc.org
Solid–liquid interfaces have received considerable attention in recent years due to their
central role in many technologically relevant fields like electrochemistry, heterogeneous …

Accelerated proton dissociation in an excited state induces superacidic microenvironments around graphene quantum dots

Y Li, S Yang, W Bao, Q Tao, X Jiang, J Li, P He… - Nature …, 2024 - nature.com
Investigating proton transport at the interface in an excited state facilitates the mechanistic
investigation and utilization of nanomaterials. However, there is a lack of suitable tools for in …

Hydrogen-bond structure dynamics in bulk water: insights from ab initio simulations with coupled cluster theory

J Liu, X He, JZH Zhang, LW Qi - Chemical science, 2018 - pubs.rsc.org
An accurate and efficient ab initio molecular dynamics (AIMD) simulation of liquid water was
made possible using the fragment-based approach (JF Liu, X. He and JZH Zhang, Phys …