Hybrid polyoxometalates as post-functionalization platforms: from fundamentals to emerging applications
Polyoxometalates (POMs) represent an important group of metal–oxo nanoclusters, typically
comprised of early transition metals in high oxidation states (mainly V, Mo and W). Many …
comprised of early transition metals in high oxidation states (mainly V, Mo and W). Many …
Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes
K Liu, W Shi, P Cheng - Coordination Chemistry Reviews, 2015 - Elsevier
Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …
recent decades because of their potential advantages to create new single-molecule …
Synthesis of 3d Metallic Single-Molecule Magnets
The phenomenon of single-molecule magnetism was established in the early 1990s with the
cluster [Mn 12 O 12 (AcO) 16 (H 2 O) 4]. Since then, a large number of compounds …
cluster [Mn 12 O 12 (AcO) 16 (H 2 O) 4]. Since then, a large number of compounds …
Synthesis, phase transformation, and morphology of hausmannite Mn3O4 nanoparticles: photocatalytic and antibacterial investigations
Abstract Nano structured Hausmannite (Mn 3 O 4) has efficacious applications in numerous
fields, such as catalytic, medical, biosensors, waste water remediation, energy storage …
fields, such as catalytic, medical, biosensors, waste water remediation, energy storage …
[MnIII4LnIII4] Calix[4]arene Clusters as Enhanced Magnetic Coolers and Molecular Magnets
G Karotsis, S Kennedy, SJ Teat… - Journal of the …, 2010 - ACS Publications
The use of methylene-bridged calix [4] arenes in 3d/4f chemistry produces a family of
clusters of general formula [MnIII4LnIII4 (OH) 4 (C4) 4 (NO3) 2 (DMF) 6 (H2O) 6](OH) 2 …
clusters of general formula [MnIII4LnIII4 (OH) 4 (C4) 4 (NO3) 2 (DMF) 6 (H2O) 6](OH) 2 …
Structural motifs and topological representation of Mn coordination clusters
Polynuclear coordination clusters have become of particular interest in recent times as a
result of their relevance to bioinorganic chemistry and to the special area of molecule-based …
result of their relevance to bioinorganic chemistry and to the special area of molecule-based …
Significant increase of the barrier energy for magnetization reversal of a single-4f-ionic single-molecule magnet by a longitudinal contraction of the coordination space
Two-electron oxidation of [{Pc (OEt) 8} 2TbIII]-[Pc (OEt) 8= dianion of 2, 3, 9, 10, 16, 17, 23,
24-octaethoxyphthalocyanine], which leads to a longitudinal contraction of the coordination …
24-octaethoxyphthalocyanine], which leads to a longitudinal contraction of the coordination …
Recent advances in 3d-4f magnetic complexes with several types of non-carboxylate organic ligands
HS Wang, K Zhang, Y Song, ZQ Pan - Inorganica Chimica Acta, 2021 - Elsevier
Since 1993, single molecule magnets (SMMs) have received a wide attention for their
potential applications in high-density information storage device, quantum computer and …
potential applications in high-density information storage device, quantum computer and …
Exploring the Influence of Diamagnetic Ions on the Mechanism of Magnetization Relaxation in {CoIII2LnIII2} (Ln = Dy, Tb, Ho) “Butterfly” Complexes
KR Vignesh, SK Langley, KS Murray… - Inorganic …, 2017 - ACS Publications
The synthesis and magnetic and theoretical studies of three isostructural heterometallic
[CoIII2LnIII2 (μ3-OH) 2 (o-tol) 4 (mdea) 2 (NO3) 2](Ln= Dy (1), Tb (2), Ho (3))“butterfly” …
[CoIII2LnIII2 (μ3-OH) 2 (o-tol) 4 (mdea) 2 (NO3) 2](Ln= Dy (1), Tb (2), Ho (3))“butterfly” …
Cluster-based single-molecule magnets
This review covers single-molecule magnets, not only focussing on developments since
2005 but also including coverage of earlier work where necessary for understanding of …
2005 but also including coverage of earlier work where necessary for understanding of …