Preparation and Post-Assembly Modification of Metallosupramolecular Assemblies from Poly(N-Heterocyclic Carbene) Ligands

MM Gan, JQ Liu, L Zhang, YY Wang, FE Hahn… - Chemical …, 2018 - ACS Publications
Although the coordination chemistry of N-heterocyclic carbenes (NHCs) with transition
metals has been explored for half a century, only in the past ten years has the chemistry of …

Cyclic iron tetra N-heterocyclic carbenes: synthesis, properties, reactivity, and catalysis

TP Schlachta, FE Kühn - Chemical Society Reviews, 2023 - pubs.rsc.org
Cyclic iron tetracarbenes are an emerging class of macrocyclic iron N-heterocyclic carbene
(NHC) complexes. They can be considered as an organometallic compound class inspired …

BIAN‐NHC ligands in transition‐metal‐catalysis: A perfect union of sterically encumbered, electronically tunable N‐Heterocyclic Carbenes?

C Chen, FS Liu, M Szostak - Chemistry–A European Journal, 2021 - Wiley Online Library
The discovery of NHCs (NHC= N‐heterocyclic carbenes) as ancillary ligands in transition‐
metal‐catalysis ranks as one of the most important developments in synthesis and catalysis …

[HTML][HTML] Editorial of special issue ruthenium complex: The expanding chemistry of the ruthenium complexes

I Dragutan, V Dragutan, A Demonceau - Molecules, 2015 - mdpi.com
Editorial of Special Issue Ruthenium Complex: The Expanding Chemistry of the Ruthenium
Complexes Next Article in Journal The Guareschi Pyridine Scaffold as a Valuable Platform for …

Polymer-supported Lewis acids and bases: Synthesis and applications

U Yolsal, TAR Horton, M Wang, MP Shaver - Progress in Polymer Science, 2020 - Elsevier
In the past decade the synthesis of novel stimuli-responsive materials has been driven by
the pursuit of new applications and, more recently, sustainable and reusable systems. Of …

Coinage Metal N‐Heterocyclic Carbene Complexes: Recent Synthetic Strategies and Medicinal Applications

S Nayak, SL Gaonkar - ChemMedChem, 2021 - Wiley Online Library
New weapons are constantly needed in the fight against cancer. The discovery of cisplatin
as an anticancer drug prompted the search for new metal complexes. The successful history …

Luminescent coinage metal complexes of carbenes

J Hossain, R Akhtar, S Khan - Polyhedron, 2021 - Elsevier
Recent years have witnessed a meteoric rise in the utilization of carbenes as ligands for the
synthesis of coinage metal complexes due to their potential application in various fields. One …

From Au11 to Au13: Tailored Synthesis of Superatomic Di-NHC/PPh3-Stabilized Molecular Gold Nanoclusters

M Bevilacqua, M Roverso, S Bogialli, C Graiff… - Inorganic …, 2023 - ACS Publications
Herein, we report a new method to synthesize molecular gold nanoclusters (AuNCs)
stabilized by phosphine (PR3) and di-N-heterocyclic carbene (di-NHC) ligands. The …

An SN1-Approach to Cross-Coupling: Deoxygenative Arylation Facilitated by the β-Silicon Effect

A Cook, A Kassymbek, A Vaezghaemi… - Journal of the …, 2024 - ACS Publications
We report a dual metal-catalyzed method for the cross-coupling of unprotected alcohols by
exploiting the β-Si effect. This deoxygenative Suzuki-Miyaura reaction tolerates a range of …

Synthesis, characterization, and biomedical evaluation of ethylene-bridged tetra-NHC Pd (ii), Pt (ii) and Au (iii) complexes, with apoptosis-inducing properties in …

WRE Büchele, TP Schlachta, AL Gebendorfer… - RSC …, 2024 - pubs.rsc.org
Synthesis and characterization of the first two cyclic ethylene-bridged tetradentate NHC
ligands, with an unsaturated (imidazole) and saturated backbone (2-imidazoline), are …