A stable mixed-valent uranium (V, VI) organic framework as a fluorescence thermometer
D Gu, W Yang, H Chen, Y Yang, X Qin… - Inorganic Chemistry …, 2021 - pubs.rsc.org
The presence of stable U (V)-containing compounds is important for the study of
radionuclides. However, pentavalent uranium is prone to disproportionation, thus U (V) …
radionuclides. However, pentavalent uranium is prone to disproportionation, thus U (V) …
Rare Bird: U+5 in Uranium Chalcogenides
Chalcogen environments tend to stabilize low oxidation states, thus making the+ 5 oxidation
state in uranium chalcogenides extremely rare. Having one unpaired electron, the …
state in uranium chalcogenides extremely rare. Having one unpaired electron, the …
New germanate and mixed cobalt germanate salt inclusion materials:[(Rb 6 F)(Rb 4 F)][Ge 14 O 32] and [(Rb 6 F)(Rb 3.1 Co 0.9 F 0.96)][Co 3.8 Ge 10.2 O 30 F 2]
Single crystals of two new germanates,[(Rb6F)(Rb4F)][Ge14O32] and [(Rb6F)(Rb3. 1Co0.
9F0. 96)][Co3. 8Ge10. 2O30F2], were synthesized via high temperature RbCl/RbF flux …
9F0. 96)][Co3. 8Ge10. 2O30F2], were synthesized via high temperature RbCl/RbF flux …
Expanding the chemistry of salt-inclusion materials: Utilizing the titanyl ion as a structure directing agent for the targeted synthesis of salt-inclusion titanium silicates
Salt-Inclusion Materials (SIMs) are a diverse and interesting class of materials. However,
their synthesis has been largely serendipitous. The targeted synthesis of SIMs requires both …
their synthesis has been largely serendipitous. The targeted synthesis of SIMs requires both …
Low temperature synthesis of oxyfluoride CsTi2O2. 85F3. 15 from a layered oxide Cs0. 68Ti1. 83O4
Q Xu, Y Su, Y Tang, Z Wang, L Lu, L Tang - Journal of Solid State Chemistry, 2022 - Elsevier
We report the successful synthesis of pyrochlore-type oxyfluoride CsTi 2 O 2.85 F 3.15 at a
low temperature from layered oxide Cs 0.68 Ti 1.83 O 4 under non-topochemical reactions …
low temperature from layered oxide Cs 0.68 Ti 1.83 O 4 under non-topochemical reactions …
Luminescence and Scintillation in the Niobium Doped Oxyfluoride Rb4Ge5O9F6:Nb
A new niobium-doped inorganic scintillating oxyfluoride, Rb4Ge5O9F6: Nb, was
synthesized in single crystal form by high-temperature flux growth. The host structure …
synthesized in single crystal form by high-temperature flux growth. The host structure …
Flux crystal growth of a new BaTa2O6 polymorph, and of the novel tantalum oxyfluoride salt inclusion phase [Ba3F] Ta4O12F: Flux dependent phase formation
A new hexagonal polymorph of BaTa 2 O 6 and a novel salt inclusion phase,[Ba 3 F] Ta 4 O
12 F, were obtained via high temperature flux crystal growth using mixed alkali …
12 F, were obtained via high temperature flux crystal growth using mixed alkali …
Electrochemical Crystal Growth of Titanium Oxyfluorides—A Strategy for Development of Electron-Doped Materials
Y Chiba, K Shibata, H Takatsu, K Fujii, M Saito… - Inorganic …, 2021 - ACS Publications
We report on the growth of single crystals of an electron-doped titanium oxyfluoride, Li2Ti (O,
F) 3, employing high-temperature electrolysis of TiO2 with a eutectic Li2MoO4–LiF melt …
F) 3, employing high-temperature electrolysis of TiO2 with a eutectic Li2MoO4–LiF melt …
Pentanary cesium titanyl/titanate silicate oxyfluorides: Syntheses and structures
Single crystals of two pentanary cesium titanyl/titanate silicate oxyfluorides, Cs 3 (TiO) Si 4 O
10 F and Cs 17 (TiO) 12 Ti 2 Si 8 O 40 F, were grown from mixed cesium halide fluxes. Cs 3 …
10 F and Cs 17 (TiO) 12 Ti 2 Si 8 O 40 F, were grown from mixed cesium halide fluxes. Cs 3 …
[PDF][PDF] Flux crystal growth of a new BaTa2O6 polymorph, and of the novel tantalum oxyfluoride salt inclusion phase [Ba3F] Ta4O12F: Flux dependent phase formation
A new hexagonal polymorph of BaTa2O6 and a novel salt inclusion phase,[Ba3F] Ta4O12F,
were obtained via high temperature flux crystal growth using mixed alkali chloride/alkali …
were obtained via high temperature flux crystal growth using mixed alkali chloride/alkali …