Pentafulvenes are a unique class of compounds that originally attracted attention due to
their propensity to display nonbenzenoid aromaticity. Subsequently, they were recognized …

This short review describes the recent emergence of organosodium chemistry, motivated by
the requirements of modern synthetic chemistry for sustainability, and powered by the use of …

The importance of the specific trialkylsilyl substituent in the cyclopentadienyl chemistry of
C5H4SiR3 ligands has been demonstrated by the synthesis of low oxidation-state thorium …

Adamantane‐type organotin chalcogenide clusters of the general composition [(RT)
4S6](R= aromatic substituent, T= Si, Ge, Sn) have extreme non‐linear optical properties that …

The reaction of (μ‐Cl) 2Ni2 (NHC) 2 (NHC= 1, 3‐bis (2, 6‐diisopropylphenyl)‐1, 3‐dihydro‐
2H‐imidazol‐2‐ylidene (IPr) or 1, 3‐bis (2, 6‐diisopropylphenyl) imidazolidin‐2‐ylidene …

Many methods report the scission of N–O bonds of aromatic heterocycles and their
subsequent functionalization. Oxidative addition is one of the presumed pathways through …

Initiation of rare earth metal-mediated vinylphosphonate polymerization with unbridged rare
earth metallocenes (Cp2LnX) follows a complex reaction pathway. Depending on the nature …

The next generation: The grafting of titanocene complexes on the surfaces of MCM‐41 and
SBA‐15 led to a new generation of anticancer drugs, which are very active against human …

The tris [(1-isopropylbenzimidazol-2-yl) dimethylsilyl] methyl thallium compound,[
TismPriBenz] Tl, reacts with Li, Na, K, and Rb to afford the respective alkali metal carbatrane …

New analogues of Cp′ 3Ln (Cp′= C5H4SiMe3, Ln= rare earth) complexes have been
synthesized with the largest and smallest lanthanides, La and Lu. Due to the smaller size of …