This Minireview describes recent advances toward the synthesis of fluoro‐,
monofluoromethyl‐, difluoromethyl‐, and trifluoromethyl‐substituted three‐membered rings …

By using water as the hydrogen source, an eco-friendly and practical protocol for the
synthesis of Z-vinyl thiocyanates through ultrasound-promoted Brønsted acid ionic liquid …

In this account the reactions of chiral N‐tert‐butylsulfinyl imines with organometallic
reagents such as organoalkaline (lithium, sodium, potassium and cesium derivatives) …

Cascade reactions are often 'employed'by nature to construct structurally diverse nitrogen-
containing heterocycles in a highly stereoselective fashion, ie, secondary metabolites …

A new and efficient synthesis of multifunctionalized perfluoroalkyl aziridines via a ruthenium–
perfluoroalkylcarbene intermediate is described. With Ru (p-Cl-TPP) CO as the catalyst, in …

A diastereo-and enantioselective approach to access chiral CF 2-functionalized aziridines
from difluorodiazoethyl phenyl sulfone (PhSO 2 CF 2 CHN 2) and in situ-formed aldimines is …

The development of synthetic methodology allowing for a strategic incorporation of fluorine
into target compounds is in a high demand in many areas of the chemical and …

Palladium-catalyzed asymmetric allylic alkylation (AAA) of vinyl benzoxazinanones has
become an important strategy for the synthesis of chiral nitrogen-containing heterocycle …

A direct thiocyanatosulfonation of alkynes with sulfinic acids and potassium thiocyanate was
developed at room temperature. This method provided a efficient and practical pathway to …

Reported in this work is a water triggered chemo‐divergent enantioselective spiro‐
annulation and cascade reaction of ortho‐quinone methides (o‐QMs) with α‐thiocyanato …