Asymmetric heterogeneous catalysis by metalloporphyrins

G Simonneaux, P Le Maux, Y Ferrand… - Coordination chemistry …, 2006 - Elsevier
The synthesis of enantiomerically pure compounds is one of the major challenges in
heterogeneous catalysis. The use of heterogeneous catalysts under ambient conditions …

Catalysis of chitosan-supported iron tetraphenylporphyrin for aerobic oxidation of cyclohexane in absence of reductants and solvents

CC Guo, G Huang, XB Zhang, DC Guo - Applied Catalysis A: General, 2003 - Elsevier
The chitosan-supported iron (III) tetraphenylporphyrin was prepared and characterized
structurally, and its ability to catalyse oxidation of cyclohexane into cyclohexanone and …

Allylic oxofunctionalization of cyclic olefins with homogeneous and heterogeneous catalysts

EF Murphy, T Mallat, A Baiker - Catalysis Today, 2000 - Elsevier
Heterogeneous catalysis and heterogenization of homogeneous catalysts are catch phrases
of modern chemistry. Here we attempt to trace the development from homogeneous to …

Mn porphyrins immobilized on non-modified and chloropropyl-functionalized mesoporous silica SBA-15 as catalysts for cyclohexane oxidation

VHA Pinto, JS Reboucas, GM Ucoski… - Applied Catalysis A …, 2016 - Elsevier
In this work, solid catalysts were prepared by the heterogenization of Mn porphyrins (MnP)
on mesoporous silica SBA-15 by two simple strategies:(1) immobilization of the three …

The oxidation of ethylbenzene by dioxygen catalysed by supported iron porphyrins derived from iron (III) tetrakis (pentafluorophenyl) porphyrin

S Evans, JRL Smith - Journal of the Chemical Society, Perkin …, 2001 - pubs.rsc.org
Chloromethylated poly (styrene) and chloropropylated silica gel have been reacted with α, ω-
diamines to give diamine modified catalyst supports which have then been covalently …

Molybdenum and tungsten complexes of composition (η5-C5R5) MR′(CO) 3 and their use as olefin epoxidation catalyst precursors

J Zhao, AM Santos, E Herdtweck, FE Kühn - Journal of Molecular Catalysis …, 2004 - Elsevier
Carbonyl complexes of formula Cp′ M (CO) 3R (M= Mo, W; R= alkyl) can be applied as
very active (TOFs up to ca. 6000h− 1; TON> 500) and selective olefin epoxidation catalysts …

Organic cross-linked electropolymers as supported oxidation catalysts: Poly ((tetrakis (9, 9 '-spirobifluorenyl) porphyrin) manganese) films

C Poriel, Y Ferrand, P Le Maux… - Inorganic …, 2004 - ACS Publications
Anodic oxidation of free base and manganese complexes of tetraspirobifluorenylporphyrins
leads to the coating of the working electrode by insoluble electroactive poly (9, 9 ' …

Alkene epoxidation with iodosylbenzene catalysed by polyionic manganese porphyrins electrostatically bound to counter-charged supports

HC Sacco, Y Iamamoto, JRL Smith - Journal of the Chemical Society …, 2001 - pubs.rsc.org
Manganese (III) complexes of tetra-anionic and tetra-cationic porphyrins have been
immobilised on counter-charged, surface-modified silica supports and on organic ion …

Poly (siloxane)-supported decacarbonyldimanganese (0) catalyst for terminal olefin hydrosilylation reactions: the effect of the support on the catalyst selectivity, activity …

HS Hilal, MA Suleiman, WJ Jondi, S Khalaf… - Journal of Molecular …, 1999 - Elsevier
A new class of supported carbonyl manganese catalyst was prepared by treating the dimeric
decacarbonyldimanganese (0), Mn2 (CO) 10, with insoluble aminated poly (siloxane) …

Highly active and selective catalysts for olefin hydrosilylation reactions using metalloporphyrins intercalated in natural clays

W Jondi, A Zyoud, W Mansour, AQ Hussein… - Reaction Chemistry & …, 2016 - pubs.rsc.org
Tetra (4-pyridyl) porphyrinato-manganese (III)(MnTPyP+) ions intercalated inside nano-and
micro-size natural clay powders effectively catalyzed the hydrosilylation reaction of 1-octene …