Photoredox-catalyzed C–H functionalization reactions

N Holmberg-Douglas, DA Nicewicz - Chemical reviews, 2021 - ACS Publications
The fields of C–H functionalization and photoredox catalysis have garnered enormous
interest and utility in the past several decades. Many different scientific disciplines have …

Bidentate directing groups: an efficient tool in C–H bond functionalization chemistry for the expedient construction of C–C bonds

S Rej, Y Ano, N Chatani - Chemical Reviews, 2020 - ACS Publications
During the past decades, synthetic organic chemistry discovered that directing group
assisted C–H activation is a key tool for the expedient and siteselective construction of C–C …

[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

From C4 to C7: innovative strategies for site-selective functionalization of indole C–H bonds

J Wen, Z Shi - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus The widespread presence of hydrocarbons makes C–H functionalization an
attractive alternative to traditional cross-coupling methods. As indole is an important …

Methodologies and strategies for selective borylation of C–Het and C–C bonds

M Wang, Z Shi - Chemical Reviews, 2020 - ACS Publications
Organoborons have emerged as versatile building blocks in organic synthesis to achieve
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …

Key Green Chemistry research areas from a pharmaceutical manufacturers' perspective revisited

MC Bryan, PJ Dunn, D Entwistle, F Gallou… - Green …, 2018 - pubs.rsc.org
In 2007 the members of the ACS Green Chemistry Institute® Pharmaceutical Roundtable
assembled a list of key green chemistry research areas to both identify transformations that …

Installing the “magic methyl”–C–H methylation in synthesis

D Aynetdinova, MC Callens, HB Hicks… - Chemical Society …, 2021 - pubs.rsc.org
The selective and efficient C–H methylation of sp2 and sp3 carbon centres has become a
powerful transformation in the synthetic toolbox. Due to the potential for profound changes to …

Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions

S Rej, A Das, N Chatani - Coordination Chemistry Reviews, 2021 - Elsevier
In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …

Rhodium‐Catalyzed C(sp2)‐ or C(sp3)−H Bond Functionalization Assisted by Removable Directing Groups

S Rej, N Chatani - Angewandte Chemie International Edition, 2019 - Wiley Online Library
In recent years, transition‐metal‐catalyzed C− H activation has become a key strategy in the
field of organic synthesis. Rhodium complexes are widely used as catalysts in a variety of …

Computational studies of carboxylate-assisted C–H activation and functionalization at group 8–10 transition metal centers

DL Davies, SA Macgregor, CL McMullin - Chemical reviews, 2017 - ACS Publications
Computational studies on carboxylate-assisted C–H activation and functionalization at
group 8–10 transition metal centers are reviewed. This Review is organized by metal and …