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Sharpless asymmetric dihydroxylation: an impressive gadget for the synthesis of natural products: a review
Sharpless asymmetric dihydroxylation is an important reaction in the enantioselective
synthesis of chiral vicinal diols that involves the treatment of alkene with osmium tetroxide …
synthesis of chiral vicinal diols that involves the treatment of alkene with osmium tetroxide …
Recent Applications and Trends in the Julia‐Kocienski Olefination
PXT Rinu, S Radhika, G Anilkumar - ChemistrySelect, 2022 - Wiley Online Library
Abstract The Julia‐Kocienski (J‐K) olefination is a modified version of Julia‐Lythgoe
olefination. In this reaction, an aldehyde or ketone is coupled with heterocycle‐bearing …
olefination. In this reaction, an aldehyde or ketone is coupled with heterocycle‐bearing …
Late-stage functionalization: total synthesis of beauveamide A and its congeners and their anticancer activities
Asymmetric total synthesis of cyclotetradepsipeptide beauveamide A has been achieved for
the first time. A macrolactamization strategy involving two possible sites has been explored …
the first time. A macrolactamization strategy involving two possible sites has been explored …
Stereoselective synthesis of the northern hemisphere of the proposed structure of neaumycin B
The stereoselective synthesis of the northern hemisphere (C20–C41) of the purported
structure of the extremely potent anticancer natural product neaumycin B has been …
structure of the extremely potent anticancer natural product neaumycin B has been …
Total synthesis of strasseriolide A
Stereoselective total synthesis of structurally intriguing antimalarial macrolide strasseriolide
A has been accomplished by adopting a convergent approach. The salient features of this …
A has been accomplished by adopting a convergent approach. The salient features of this …
Yamaguchi esterification: a key step toward the synthesis of natural products and their analogs—a review
The Yamaguchi reagent, based on 2, 4, 6-trichlorobenzoyl chloride (TCBC) and 4-
dimethylaminopyridine (DMAP), is an efficient tool for conducting the intermolecular …
dimethylaminopyridine (DMAP), is an efficient tool for conducting the intermolecular …
Total synthesis of antibacterial macrolide sorangiolide A
A convergent route for the asymmetric total synthesis of antibacterial macrolide sorangiolide
A has been developed for the first time. The key feature of this synthesis includes Krische …
A has been developed for the first time. The key feature of this synthesis includes Krische …
Stereoselective synthesis of thailandamide A methyl ester
A convergent strategy for the stereoselective synthesis of the methyl ester of the structurally
challenging and highly labile antibacterial polyene polyketide natural product thailandamide …
challenging and highly labile antibacterial polyene polyketide natural product thailandamide …
Total Synthesis of Lipopeptide Bacilotetrin C: Discovery of Potent Anticancer Congeners Promoting Autophagy
A convergent strategy for the first total synthesis of the lipopeptide bacilotetrin C has been
developed. The key features of this synthesis include Crimmins acetate aldol, Steglich …
developed. The key features of this synthesis include Crimmins acetate aldol, Steglich …
Asymmetric Total Synthesis of Amphirionin-2
A convergent route for the asymmetric total synthesis of potent anticancer polyketide natural
product amphirionin-2 has been developed. Our initial synthetic trials revealed that the …
product amphirionin-2 has been developed. Our initial synthetic trials revealed that the …