Conspectus Chain-walking offers extensive opportunities for innovating synthetic methods
that involve constructing chemical bonds at unconventional sites. This approach provides …

Chiral boronic esters are a class of versatile building blocks. We describe herein an
asymmetric nickel-catalyzed borylative coupling of terminal alkenes with nonactivated alkyl …

Comprehensive Summary α‐Olefins as aliphatic terminal alkenes could be obtained easily
from numerous contemporary synthetic reactions as well as petrochemical industry, and also …

Radical reactions play an important role in modern organic synthetic chemistry. The
generation of carbon radicals from the homolytic cleavage of carbon–metal bonds has been …

Herein, we disclose a Ni-catalyzed 1, 1-difunctionalization of unactivated terminal alkenes
that enables the incorporation of two different heteroatom motifs across an olefin backbone …

While chain‐walking stimulates wide interest in both polymerization and organic synthesis,
site‐and stereoselective control of chain‐walking on rings is still a challenging task in the …

Polysubstituted alkenes are an important class of organic intermediates that widely exist in
various natural products and drug molecules. Herein, we reported a stereoselective …

Abstract An oxidative [3+ 2+ 1] cyclization of enaminones and N‐alkenyl‐2‐pyrrolidinone is
described for the synthesis of 4‐alkylated 1, 4‐dihydropyridines (1, 4‐DHPs). By using …

The trifunctionalization of alkenes has emerged as a versatile strategy for the efficient
construction of diverse structural units and complex molecules in synthetic chemistry …

Miyaura borylation is widely recognized as one of the most reliable methods for constructing
an organoboron compound. Reported herein is Pd (0)-catalyzed asymmetric three …