Designing crystallization in phase-change materials for universal memory and neuro-inspired computing

W Zhang, R Mazzarello, M Wuttig, E Ma - Nature Reviews Materials, 2019 - nature.com
The global demand for data storage and processing has increased exponentially in recent
decades. To respond to this demand, research efforts have been devoted to the …

Chalcogenides by design: functionality through metavalent bonding and confinement

BJ Kooi, M Wuttig - Advanced materials, 2020 - Wiley Online Library
A unified picture of different application areas for incipient metals is presented. This
unconventional material class includes several main‐group chalcogenides, such as GeTe …

Crystal growth within a phase change memory cell

A Sebastian, M Le Gallo, D Krebs - Nature communications, 2014 - nature.com
In spite of the prominent role played by phase change materials in information technology, a
detailed understanding of the central property of such materials, namely the phase change …

Unraveling Crystallization Mechanisms and Electronic Structure of Phase‐Change Materials by Large‐Scale Ab Initio Simulations

Y Xu, Y Zhou, XD Wang, W Zhang, E Ma… - Advanced …, 2022 - Wiley Online Library
Abstract Ge–Sb–Te (“GST”) alloys are leading phase‐change materials for digital memories
and neuro‐inspired computing. Upon fast crystallization, these materials form rocksalt‐like …

Suppressing structural relaxation in nanoscale antimony to enable ultralow‐drift phase‐change memory applications

B Chen, XP Wang, F Jiao, L Ning, J Huang… - Advanced …, 2023 - Wiley Online Library
Phase‐change random‐access memory (PCRAM) devices suffer from pronounced
resistance drift originating from considerable structural relaxation of phase‐change …

Existence of multiple critical cooling rates which generate different types of monolithic metallic glass

JEK Schawe, JF Löffler - Nature communications, 2019 - nature.com
Via fast differential scanning calorimetry using an Au-based glass as an example, we show
that metallic glasses should be classified into two types of amorphous/monolithic glass. The …

Switching between Crystallization from the Glassy and the Undercooled Liquid Phase in Phase Change Material Ge2Sb2Te5

J Pries, S Wei, M Wuttig, P Lucas - Advanced materials, 2019 - Wiley Online Library
Controlling crystallization kinetics is key to overcome the temperature–time dilemma in
phase change materials employed for data storage. While the amorphous phase must be …

Fragile‐to‐strong crossover in supercooled liquid Ag‐In‐Sb‐Te studied by ultrafast calorimetry

J Orava, DW Hewak, AL Greer - Advanced Functional Materials, 2015 - Wiley Online Library
Phase‐change random‐access memory relies on the reversible crystalline‐glassy phase
change in chalcogenide thin films. In this application, the speed of crystallization is critical for …

Fast and slow crystal growth kinetics in glass-forming melts

J Orava, AL Greer - The Journal of chemical physics, 2014 - pubs.aip.org
Published values of crystal growth rates are compared for supercooled glass-forming liquids
undergoing congruent freezing at a planar crystal-liquid interface. For the purposes of …

[HTML][HTML] Classical-nucleation-theory analysis of priming in chalcogenide phase-change memory

J Orava, AL Greer - Acta Materialia, 2017 - Elsevier
Abstract The chalcogenide Ge 2 Sb 2 Te 5 (GST) is of interest for use in phase-change
memory. Crystallization is the rate-limiting step for memory operation, and can be …