Nitroxide-mediated polymerization
Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …
(CLRP) technique that enables the design of well-defined, functional and complex …
Modeling and theoretical development in controlled radical polymerization
Controlled radical polymerization (CRP) systems have gained increasing interests for the
past two decades. Numerous publications may be found in the literature reporting …
past two decades. Numerous publications may be found in the literature reporting …
Unraveling reaction pathways and specifying reaction kinetics for complex systems
Many natural and industrial processes involve a complex set of competing reactions that
include several different species. Detailed kinetic modeling of such systems can shed light …
include several different species. Detailed kinetic modeling of such systems can shed light …
Flow mediated metal-free PET-RAFT polymerisation for upscaled and consistent polymer production
Four commercially available xanthene based organo-dyes, eosin Y, erythrosin B, phloxine
B, and rose bengal, were investigated for their ability to catalyse PET-RAFT polymerisation …
B, and rose bengal, were investigated for their ability to catalyse PET-RAFT polymerisation …
Numerical techniques for the solution of the molecular weight distribution in polymerization mechanisms, state of the art
E Saldívar‐Guerra - Macromolecular Reaction Engineering, 2020 - Wiley Online Library
The molecular weight distribution (MWD) is possibly the most important characteristic of a
polymer. Polymers derive many of their physical properties from their MWD. Therefore, since …
polymer. Polymers derive many of their physical properties from their MWD. Therefore, since …
CFD modeling for the prediction of molecular weight distribution in the LDPE autoclave reactor: Effects of non-ideal mixing
A commercial Low-density polyethylene (LDPE) reactor was modeled to investigate the
effects of highly nonlinear hydrodynamics in an industrial-scale autoclave reactor on the …
effects of highly nonlinear hydrodynamics in an industrial-scale autoclave reactor on the …
Model‐based production of polymer chains having precisely designed end‐to‐end gradient copolymer composition and chain topology distributions in controlled …
Polymer chain microstructures, such as copolymer composition distribution (CCD) and
topology, play an important role in determining materials properties of the polymer products …
topology, play an important role in determining materials properties of the polymer products …
CFD modeling of the ethylene–vinyl acetate copolymerization autoclave reactor: Effects of comonomer ratio on reactor dynamics and copolymer properties
Computational fluid dynamics (CFD) modeling of an industrial ethylene–vinyl acetate
autoclave copolymerization reactor was conducted to evaluate the effects of comonomer …
autoclave copolymerization reactor was conducted to evaluate the effects of comonomer …
Simultaneous Regulation of Molecular Weight Distribution and Composition through RDRP in a Continuous-Flow Reactor: A Kinetic Modeling
H Xue, J He - Macromolecules, 2025 - ACS Publications
Regulating the molecular weight distribution (MWD) and copolymer composition is of great
significance for controlling the properties of polymer materials. Combining reversible …
significance for controlling the properties of polymer materials. Combining reversible …
Modeling of α-olefin copolymerization with chain-shuttling chemistry using dual catalysts in stirred-tank reactors: Molecular weight distributions and copolymer …
M Zhang, TW Karjala, P Jain - Industrial & Engineering Chemistry …, 2010 - ACS Publications
We report a kinetic model of chain-shuttling copolymerization using dual catalysts for
solution α-olefin polymerization processes. This model focuses on predicting polymer …
solution α-olefin polymerization processes. This model focuses on predicting polymer …