C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Phenalenyl, a zigzag-edged odd alternant hydrocarbon unit can be found in the graphene
nanosheet. Hückel molecular orbital calculations indicate the presence of a nonbonding …

Nitrogen-containing compounds, such as amines, enamines, and imines, are valuable and
commercially important bulk chemicals, specialty chemicals, and pharmaceuticals. 1 Among …

Organometallic chemistry is generally considered the key to homogeneous catalysis, which,
although a century old, is still today a very dynamic discipline. 1 The past decade has seen …

The discovery, study, and implementation of the Co-and Mn-catalyzed hydrohydrazination
and hydroazidation reactions of olefins are reported. These reactions are equivalent to direct …

Reaction of benzyl (2, 2-diphenyl-4, 5-hexadienyl) carbamate (4) with a catalytic 1: 1 mixture
of Au [P (t-Bu) 2 (o-biphenyl)] Cl (2) and AgOTf (5 mol%) in dioxane at 25° C for 45 min led to …

Nitrogen–carbon bonds are ubiquitous in products ranging from chemical feedstock to
pharmaceuticals. As ammonia is among the least expensive bulk chemicals produced in the …

The β-diketiminate-stabilized calcium amide complex [{ArNC (Me) CHC (Me) NAr} Ca {N
(SiMe3) 2}(THF)](Ar= 2, 6-diisopropylphenyl) and magnesium methyl complex [{ArNC (Me) …

This Perspective article outlines some of the recent advancements completed in the
development of (chiral) metal-free and late-transition metal catalysts for the inter-and …

Nitrogen-containing heterocyclic systems have attracted considerable interest over the years
because they form the core structures, and are key intermediates, of natural products.[1] One …