A review on development of solid phase microextraction fibers by sol–gel methods and their applications

A Kumar, AK Malik, DK Tewary, B Singh - Analytica chimica acta, 2008 - Elsevier
Solid phase microextraction (SPME) is an innovative, solvent free technology that is fast,
economical and versatile. SPME is a fiber coated with a liquid (polymer), a solid (sorbent) or …

Entrapment of biocatalysts in hydrophobic sol‐gel materials for use in organic chemistry

MT Reetz - Advanced Materials, 1997 - Wiley Online Library
Lipases trapped in hydrophobic organic/inorganic materials result in chemically and
thermally stable heterogeneous catalysts that display unusually high catalytic activities. The …

Sol–gel stationary phases for capillary electrochromatography

W Li, DP Fries, A Malik - Journal of Chromatography A, 2004 - Elsevier
A review is presented on the current state of the art and future trends in the development of
sol–gel stationary phases for capillary electrochromatography (CEC). The design and …

Cage-like structure formation during sol–gel polymerization of glycidyloxypropyltrimethoxysilane

L Matějka, O Dukh, J Brus, WJ Simonsick Jr… - Journal of non …, 2000 - Elsevier
The sol–gel polymerization of 3-glycidyloxypropyltrimethoxysilane (GTMS) was followed by
size exclusion chromatography and 29Si NMR. Extensive non-random cyclization under …

Kinetic and thermodynamic issues in the early stages of sol-gel processes using silicon alkoxides

J Šefčik, AV McCormick - Catalysis Today, 1997 - Elsevier
An understanding of the chemical processes that take place in the earliest stages of a sol-
gel preparation can provide the potential to better control microstructural evolution of a …

Thermochemistry of aqueous silicate solution precursors to ceramics

J Šefčík, AV McCormick - AIChE Journal, 1997 - Wiley Online Library
A quantitative understanding of the thermochemistry of silicate solution systems is necessary
for the design, optimization and control of sol‐gel, colloid and zeolite preparations. This …

Inverse vulcanization of norbornenylsilanes: soluble polymers with controllable molecular properties via siloxane bonds

JM Scheiger, M Hoffmann, P Falkenstein… - Angewandte Chemie …, 2022 - Wiley Online Library
The inverse vulcanization produces high sulfur content polymers from alkenes and
elemental sulfur. Control over properties such as the molar mass or the solubility of polymers …

[BUCH][B] Spectroscopic Properties of Inorganic and Organometallic Compounds: Volume 26

JH Carpenter, SJ Clark, KB Dillon, JD Donaldson… - 2007 - books.google.com
Spectroscopic Properties of Inorganic and Organometallic Compounds provides a unique
source of information on an important area of chemistry. Divided into sections mainly …

Study of the effects of progressive changes in alkoxysilane structure on sol− gel reactivity

B Tan, SE Rankin - The Journal of Physical Chemistry B, 2006 - ACS Publications
Effects of the structure of an alkoxysilane on the early reaction kinetics of sol− gel
polymerization are investigated in basic and acidic conditions. Six silanes, including …

Kinetics of the acid-catalyzed hydrolysis of tetraethoxysilane (TEOS) by 29Si NMR spectroscopy and mathematical modeling

JC Echeverría, P Moriones, G Arzamendi… - Journal of Sol-Gel …, 2018 - Springer
Tetraethoxysilane (TEOS) is widely used to synthesize siliceous material by the sol–gel
process. However, there is still some disagreement about the nature of the limiting step in …