Visible-light induced dearomatization reactions

YZ Cheng, Z Feng, X Zhang, SL You - Chemical Society Reviews, 2022 - pubs.rsc.org
Dearomatization reactions provide rapid access to structurally complex three-dimensional
molecules from simple aromatic compounds. Plenty of reports have demonstrated their …

Recent development of aryl diazonium chemistry for the derivatization of aromatic compounds

F Mo, D Qiu, L Zhang, J Wang - Chemical Reviews, 2021 - ACS Publications
Aryl diazonium salts are versatile building blocks in organic synthesis. In light of the ever-
increasing importance of aryl diazonium salts spanning most disciplines of the chemical …

Recent Advances in the Construction of Spiro Compounds via Radical Dearomatization

WC Yang, MM Zhang, JG Feng - Advanced Synthesis & …, 2020 - Wiley Online Library
The field in dearomatization of aromatic compounds for the construction of spirocycle
compounds has been developed rapidly over the last two decades and it provides …

Recent progress and emerging technologies towards a sustainable synthesis of sulfones

S Liang, K Hofman, M Friedrich, J Keller… - …, 2021 - Wiley Online Library
Sulfones play a pivotal role in modern organic chemistry. They are highly versatile building
blocks and find various applications as drugs, agrochemicals, or functional materials …

Advances in photochemical and electrochemical incorporation of sulfur dioxide for the synthesis of value-added compounds

SP Blum, K Hofman, G Manolikakes… - Chemical …, 2021 - pubs.rsc.org
Organic photochemistry and electrochemistry currently receive tremendous attention in
organic synthesis as both techniques enable the reagent-less activation of organic …

Visible‐Light Induced Fixation of SO2 into Organic Molecules with Polypyridine Chromium(III) Complexes

S Sittel, AC Sell, K Hofmann, C Wiedemann… - …, 2023 - Wiley Online Library
Incorporation of sulfur dioxide into organic compounds is achieved by a photocatalytic
approach using sensitizers made from earth‐abundant chromium (III) ions and visible light …

Visible-light-induced metal-free cascade cyclization of N-arylpropiolamides to 3-phosphorylated, trifluoromethylated and thiocyanated azaspiro [4.5] trienones

FL Zeng, XL Chen, K Sun, HL Zhu, XY Yuan… - Organic Chemistry …, 2021 - pubs.rsc.org
Photocatalytic strategies for the preparation of 3-phosphoryl/trifluoromethyl/thiocyanato
azaspiro [4.5] trienones via a radical-initiated cascade annulation reaction of N …

Electrochemical Oxidative Halogenation of N-Aryl Alkynamides for the Synthesis of Spiro[4.5]trienones

K Yu, X Kong, J Yang, G Li, B Xu… - The Journal of Organic …, 2020 - ACS Publications
We developed a green method for the synthesis of spiro [4.5] trienones through an
electrochemical oxidative halocyclization with N-aryl alkynamides. This reaction was …

DABSO as a SO 2 gas surrogate in the synthesis of organic structures

MS Hashtroudi, VF Vavsari, S Balalaie - Organic & Biomolecular …, 2022 - pubs.rsc.org
1, 4-Diazabicyclo [2.2. 2] octane bis (sulfur dioxide), DABCO· SO2, or DABSO, a bench-
stable colorless solid, is industrially produced by the reaction of DABCO with condensed …

Asymmetric Dearomatization of Phenols via Ligand‐Enabled Cooperative Gold Catalysis

Y Zhang, K Zhao, X Li, CD Quintanilla… - Angewandte Chemie …, 2023 - Wiley Online Library
By employing a chiral bifunctional phosphine ligand, a gold (I)‐catalyzed efficient and highly
enantioselective dearomatization of phenols is achieved via versatile metal‐ligand …