This review summarizes the known electrochemistry of metal-metal bonded diruthenium
complexes containing an air-stable Ru 2 4+, Ru 2 5+ or Ru 2 6+ core or an in-situ generated …

Recent evolutions, essentially in the last 15 years, are reviewed in the field of molecular
mixed‐valent compounds and their properties. The considered systems are of the type Mn …

Polyoxometalates (POMs) are unconventional electro-active molecules with a great potential
for applications in molecular memories, providing efficient processing steps onto electrodes …

Molecular junctions, which involve sandwiching molecular structures between electrodes,
play a crucial role in molecular electronics. Recent advances in this field have revealed the …

We describe the chemistry of 3d metal alkynyls based on polyaza macrocyclic ligands, an
emerging area of alkynyl chemistry that has previously been dominated by 4d and 5d metals …

The amidinate anions have been widely used in the formation of dinuclear complexes with
paddlewheel structure. The higher donor character of this type of ligands, compared to …

The continuing miniaturization of microelectronics is pushing advanced manufacturing into
nanomanufacturing. Nanojoining is a bottom-up assembly technique that enables functional …

Reported herein are new Fe bis-alkynyl complexes [FeIII (L)(C2R) 2] BPh4 based on tetra
imine macrocycle (L= HMTI= meso-5, 5, 7, 12, 12, 14-hexamethyl-1, 4, 8, 11 …

Control of charge carriers that transport through the molecular junctions is essential for
thermoelectric materials. In general, the charge carrier depends on the dominant conduction …

Immobilization of polyoxometalates (POMs) onto oxides is relevant to many applications in
the fields of catalysis, energy conversion/storage, or molecular electronics. Optimization and …