Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …

Advances in hypervalent iodine chemistry have put the field on the precipice of a second
golden age; the first being pioneered in the 1990s. During that period, C–C bond forming …

Here we report a contractive synthesis of multisubstituted cyclobutanes containing multiple
stereocenters from readily accessible pyrrolidines using iodonitrene chemistry. Mediated by …

Summary A strategy for C–H functionalization of arenes and heteroarenes has been
developed to allow site-selective incorporation of various anions, including Cl, Br, OMs, OTs …

Here we report the challenging O‐trifluoromethylation of carboxylic acids via the formation
and activation of acyloxy (phenyl) trifluoromethyl‐λ3‐iodanes. The method provides an easy …

A simple process for the oxy‐monofluoromethylation of alkenes is described. In combination
with visible‐light copper (I) photoredox catalysis, an easily accessible iodine (III) reagent …

Understanding the role of boranes in hypervalent iodine chemistry will open up new
reactivities which can be utilised in organic synthesis. Due to similar reactivities, λ3-iodanes …

Recent discoveries on the structure of iodine( iii ) reagents and their use in cross-nucleophile
coupling - Chemical Science (RSC Publishing) DOI:10.1039/D0SC03266B Royal Society of …

This communication describes a method for the nucleophilic radiofluorination of electron-
rich arenes. The reaction involves the initial C (sp2)–H functionalization of an electron-rich …

The umpolung alkylation of silyl enol ethers with an iodonium (III) ylide proceeds under mild
conditions to afford various 1, 4‐dicarbonyl compounds in high yields in the presence of a …