Structure and nanostructure in ionic liquids

R Hayes, GG Warr, R Atkin - Chemical reviews, 2015 - ACS Publications
Much of chemistry is concerned with the study of reactions and processes in solution, that is,
where liquids are used as solvents. 2, 3 The solvent is the (excess) liquid phase in which …

Scattering from ionic liquids

T Murphy, R Atkin, GG Warr - Current Opinion in Colloid & Interface Science, 2015 - Elsevier
Research into the properties and applications of ionic liquids (ILs) has accelerated over the
last few decades, driven principally by the advanced reaction kinetics and specificity they …

Polymer-ionic liquid ternary systems for Li-battery electrolytes: Molecular dynamics studies of LiTFSI in a EMIm-TFSI and PEO blend

LT Costa, B Sun, F Jeschull, D Brandell - The Journal of chemical …, 2015 - pubs.aip.org
This paper presents atomistic molecular dynamics simulation studies of lithium bis
(trifluoromethane) sulfonylimide (LiTFSI) in a blend of 1-ethyl-3-methylimidazolium (EMIm) …

Polymer conformation determination by NMR spectroscopy: comparative diffusion ordered 1 H-NMR spectroscopy of poly (2-ethyl-2-oxazoline) s and poly (ethylene …

BD Monnery, VV Jerca, R Hoogenboom, T Swift - Polymer Chemistry, 2024 - pubs.rsc.org
Diffusion ordered 1H-NMR spectroscopy (DOSY) is a useful, non-destructive technique for
analysing polymer hydrodynamic size and intrinsic/solution viscosity. However, to date there …

Influence of molecular weight on ion-transport properties of polymeric ionic liquids

JR Keith, S Mogurampelly, F Aldukhi… - Physical Chemistry …, 2017 - pubs.rsc.org
We report the results of atomistic molecular dynamics simulations on polymerized 1-butyl-3-
vinylimidazolium-hexafluorophosphate ionic liquids, studying the influence of the polymer …

Structure and intermolecular interactions in aqueous solutions of polyethylene glycol

L Almásy, OP Artykulnyi, VI Petrenko, OI Ivankov… - Molecules, 2022 - mdpi.com
Aqueous solutions of polyethylene glycol are studied by small-angle neutron scattering over
a broad range of polymer molecular masses and concentrations. The scattering data were …

[HTML][HTML] Structure and mechanisms underlying ion transport in ternary polymer electrolytes containing ionic liquids

S Mogurampelly, V Ganesan - The Journal of Chemical Physics, 2017 - pubs.aip.org
We use all atom molecular dynamics simulations to investigate the influence of 1-butyl-3-
methylimidazolium hexafluorophosphate (BMIMPF 6) ionic liquid on the structure and …

Polymers in molten inorganic salt hydrate phase change materials: solubility and gelation

KK Rajagopalan, P Karimineghlani, X Zhu… - Journal of Materials …, 2021 - pubs.rsc.org
Inorganic salt hydrates are of interest as phase change materials (PCMs) for thermal energy
storage because of their unique properties, such as high latent heats of fusion, moderate …

Entropic mechanism for the lower critical solution temperature of poly (ethylene oxide) in a room temperature ionic liquid

E Choi, A Yethiraj - ACS Macro Letters, 2015 - ACS Publications
Polymers exhibit interesting phase behavior in room temperature ionic liquids. For example
poly (ethylene oxide)(PEO) displays a lower critical solution temperature (LCST) in …

Osmolyte-induced conformational stabilization of a hydrophobic polymer

P Nanavare, S Sarkar, AB Jena… - Physical Chemistry …, 2024 - pubs.rsc.org
Elucidating the mechanistic role of osmolytes on conformations of hydrophobic prototypical
macromolecules in principle is the step** stone towards understanding the effect of …