The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

Chiral organoboronates have played a critical role in organic chemistry and in the
development of materials science and pharmaceuticals. Much effort has been devoted to …

This Review summarizes the advances in the construction of all-carbon quaternary
stereocenters via catalytic enantioselective desymmetrization of prochiral and meso …

Non‐racemic chiral boronic esters are recognised as immensely valuable building blocks in
modern organic synthesis. Their stereospecific transformation into a variety of functional …

Until recently, computational tools were mainly used to explain chemical reactions after
experimental results were obtained. With the rapid development of software and hardware …

The Suzuki–Miyaura cross-coupling reaction has emerged as one of the most powerful
methods for the construction of carbon–carbon bonds. Though most widely utilized for the …

The development of an enantioselective catalytic Suzuki–Miyaura reaction that applies to
meso 1, 2-diborylcycloalkanes is described. This reaction provides a modular route to …

Over the past two decades, organotrifluoroborates have evolved from being chemical
curiosities to important reagents for the elaboration of organic molecules. Aside from their …

The integration of amidyl radicals with cross-coupling chemistry opens new avenues for
reaction design. However, the lack of efficient methods for the generation of such radical …

We report a two-step strategy for diverse hydrofunctionalizations of aliphatic internal alkenes
with high regioselectivity and enantioselectivity. This process comprises a copper-catalyzed …