Atomically Dispersed Pt1–Polyoxometalate Catalysts: How Does Metal–Support Interaction Affect Stability and Hydrogenation Activity?
Unlike nanostructured metal catalysts, supported single-atom catalysts (SACs) contain only
atomically dispersed metal atoms, hinting at much more pronounced metal–support effects …
atomically dispersed metal atoms, hinting at much more pronounced metal–support effects …
Hard x-ray emission spectroscopy: a powerful tool for the characterization of magnetic semiconductors
This review aims to introduce the x-ray emission spectroscopy (XES) and resonant inelastic
x-ray scattering (RIXS) techniques to the materials scientist working with magnetic …
x-ray scattering (RIXS) techniques to the materials scientist working with magnetic …
Reflections on hard X-ray photon-in/photon-out spectroscopy for electronic structure studies
An increasing community of researchers in various fields of natural sciences is combining X-
ray absorption with X-ray emission spectroscopy (XAS–XES) to study electronic structure …
ray absorption with X-ray emission spectroscopy (XAS–XES) to study electronic structure …
Valence to core X‐ray emission spectroscopy
E Gallo, P Glatzel - Advanced Materials, 2014 - Wiley Online Library
This Progress Report discusses the chemical sensitivity of Kβ valence to core X‐ray
emission spectroscopy (vtc‐XES) and its applications for investigating 3d‐transition‐metal …
emission spectroscopy (vtc‐XES) and its applications for investigating 3d‐transition‐metal …
Determination of Hund's coupling in oxides using resonant inelastic x-ray scattering
We report resonant inelastic x-ray scattering (RIXS) measurements on ordered double-
perovskite samples containing Re 5+ and Ir 5+ with 5 d 2 and 5 d 4 electronic configurations …
perovskite samples containing Re 5+ and Ir 5+ with 5 d 2 and 5 d 4 electronic configurations …
Promotion of Pd nanoparticles by Fe and formation of a Pd3Fe intermetallic alloy for propane dehydrogenation
Silica supported Pd (∼ 2 nm), Pd 3 Fe (∼ 2 nm) and Pd 3 Fe_large (∼ 12 nm) catalysts
were synthesized and tested for propane dehydrogenation at 510° C. At the 10 …
were synthesized and tested for propane dehydrogenation at 510° C. At the 10 …
Structure, bonding, and stability of mercury complexes with thiolate and thioether ligands from high-resolution XANES spectroscopy and first-principles calculations
We present results obtained from high energy-resolution L3-edge XANES spectroscopy and
first-principles calculations for the structure, bonding, and stability of mercury (II) complexes …
first-principles calculations for the structure, bonding, and stability of mercury (II) complexes …
High-energy resolution X-ray absorption and emission spectroscopy reveals insight into unique selectivity of La-based nanoparticles for CO2
The lanthanum-based materials, due to their layered structure and f-electron configuration,
are relevant for electrochemical application. Particularly, La2O2CO3 shows a prominent …
are relevant for electrochemical application. Particularly, La2O2CO3 shows a prominent …
Intrinsic deviations in fluorescence yield detected x-ray absorption spectroscopy: the case of the transition metal L2, 3 edges
Fluorescence yield (FY) detected x-ray absorption spectra (XAS) of 3d transition metal ions
are calculated from the integrated 2p3d resonant x-ray emission spectra. The resulting FY …
are calculated from the integrated 2p3d resonant x-ray emission spectra. The resulting FY …
Spin-orbit coupling in a half-filled shell: The case of
P Warzanowski, M Magnaterra, G Schlicht, Q Faure… - Physical Review B, 2024 - APS
The half-filled t 2 g shell of the t 2 g 3 configuration usually, in LS coupling, hosts a S= 3/2
ground state with quenched orbital moment. This state is not Jahn-Teller active. Sufficiently …
ground state with quenched orbital moment. This state is not Jahn-Teller active. Sufficiently …