Emerging Halide Solid Electrolytes for Sodium Solid‐State Batteries: Structure, Conductivity, Paradigm of Applications

Z Wei, LF Nazar, J Janek - Batteries & Supercaps, 2024 - Wiley Online Library
Solid‐state sodium batteries (SSSBs) hold great promise for the development of safe, low‐
cost energy storage devices. Develo** solid electrolyte (SE) materials with high ionic …

Structure designing, interface engineering, and application prospects for sodium‐ion inorganic solid electrolytes

M Wu, H Liu, X Qi, D Li, C Wang, CW Nan, LZ Fan - InfoMat, 2024 - Wiley Online Library
All‐solid Na‐ion batteries (ASNIBs) present significant potential for integration into large‐
scale energy storage systems, capitalizing on their abundant raw materials, exemplary …

4 V Na Solid State Batteries Enabled by a Scalable Sodium Metal Oxyhalide Solid Electrolyte

L Zhou, JD Bazak, C Li, LF Nazar - ACS Energy Letters, 2024 - ACS Publications
All-solid-state sodium batteries (ASSSBs) are viable candidates for large scale energy
storage that could vie with lithium. Ductile solid catholytes for such cells that can be …

On the influence of the coherence length on the ionic conductivity in mechanochemically synthesized sodium-conducting halides, Na 3− x In 1− x Zr x Cl 6

T Zhao, AN Sobolev, XM de Irujo Labalde… - Journal of Materials …, 2024 - pubs.rsc.org
The Na+ ionic conductivity of ball milled Na3− xIn1− xZrxCl6 rises with increasing Zr content,
while that in the subsequently annealed Na3− xIn1− xZrxCl6 compounds reaches a …

NaTaCl6: Chloride as the End-Member of Sodium-Ion Conductors

K Motohashi, H Tsukasaki, A Sakuda, S Mori… - ACS Materials …, 2024 - ACS Publications
All-solid-state sodium batteries are beneficial owing to their high energy density, safety, and
abundance. Solid electrolytes are key materials in the improvement of the construction and …

A perspective on the building blocks of a solid-state battery: from solid electrolytes to quantum power harvesting and storage

BM Gomes, JFR Moutinho, MH Braga - Journal of Materials Chemistry …, 2024 - pubs.rsc.org
We present a comprehensive perspective on the fundamental components of a solid-state
battery, starting from all-solid-state electrolytes and extending to quantum power harvesting …

Sodium Metal Oxyhalides NaMOCl4 (M = Nb, Ta) with High Ionic Conductivities

T Zhao, B Samanta, XM de Irujo-Labalde… - ACS Materials …, 2024 - ACS Publications
Halide-based ionic conductors have attracted growing interest as solid electrolyte
candidates because of their suggested electrochemical oxidation stability and deformability …

Synthesis-Controlled Polymorphism and Anion Solubility in the Sodium-Ion Conductor Na3InCl6–xBrx (0 ≤ x ≤ 2)

T Zhao, MA Kraft, WG Zeier - Inorganic Chemistry, 2023 - ACS Publications
Motivated by the significant transport property improvement of the anion-substituted lithium
metal halides, a series of anion mixed solid solutions of Na3InCl6–x Br x (0≤ x≤ 2) are …

Na2.5Cr0.5Zr0.5Cl6: A New Halide‐Based Fast Sodium‐Ion Conductor

L Wang, Z Song, X Lou, Y Chen, T Wang, Z Wang… - Small, 2024 - Wiley Online Library
All‐solid‐state batteries employing solid electrolytes (SEs) have received widespread
attention due to their high safety. Recently, lithium halides are intensively investigated as …

How crystal structure and microstructure can influence the sodium-ion conductivity in halide perovskites

XM de Irujo-Labalde, T Zhao, B Samanta… - Journal of Materials …, 2024 - pubs.rsc.org
The perovskite crystal structure with nominal composition ABX3 offers a very flexible
framework for sodium halide ionic conductors, an aspect not well defined in the current …