Chemical compatibilization, macro-, and microphase separation of heteroassociative polymers
SPO Danielsen - Macromolecules, 2023 - ACS Publications
A mean-field equilibrium theory for reversible network formation due to heterotypic pairwise
interactions in mixtures of associative polymers is extended via a weak inhomogeneity …
interactions in mixtures of associative polymers is extended via a weak inhomogeneity …
Formation of Disordered Cocontinuous Phases by Randomly Linked Star Copolymers
Cocontinuous polymeric nanostructures have garnered significant interest due to their ability
to combine different properties of two separate polymer domains. Randomly linked …
to combine different properties of two separate polymer domains. Randomly linked …
Effects of randomly end-linked copolymer network parameters on the formation of disordered cocontinuous phases
Randomly end-linked copolymer networks (RECNs) provide a robust route to cocontinuous
nanoscale structures, yielding opportunities to integrate desirable and distinct properties of …
nanoscale structures, yielding opportunities to integrate desirable and distinct properties of …
Self-consistent field approach for cross-linked copolymer materials
F Schmid - Physical Review Letters, 2013 - APS
A generalized self-consistent field approach for polymer networks with a fixed topology is
developed.<? format?> It is shown that the theory reproduces the localization of cross-links …
developed.<? format?> It is shown that the theory reproduces the localization of cross-links …
The structure and phase transitions in polymer blends, diblock copolymers and liquid crystalline polymers: The Landau‐Ginzburg approach
The polymer systems are discussed in the framework of the Landau‐Ginzburg model. The
model is derived from the mesoscopic Edwards Hamiltonian via the conditional partition …
model is derived from the mesoscopic Edwards Hamiltonian via the conditional partition …
Stress-induced ordering in microphase-separated multicomponent networks
Polymer blends, mixtures, or block copolymers can be cross-linked in a homogeneous state
forming a multicomponent network. Upon cooling such network, the repulsion between …
forming a multicomponent network. Upon cooling such network, the repulsion between …
Monte Carlo study of the microphase separation of cross-linked polymer blends
S Lay, JU Sommer, A Blumen - The Journal of Chemical Physics, 2000 - pubs.aip.org
We present large scale Monte Carlo simulations of polymer blends, cross-linked in the
absence of interactions and quenched into the two-phase region. Our results show, in …
absence of interactions and quenched into the two-phase region. Our results show, in …
Pore size distribution induced by microphase separation: effect of the leaving group during polycondensation
A mean field theoretical model is developed to investigate the porosity of cross-linked
copolymer networks formed by polycondensation. It is found that cross-linking induces …
copolymer networks formed by polycondensation. It is found that cross-linking induces …
Microphase separation of crosslinked polymer blends in solution
M Benhamou, A Derouiche, A Bettachy - The Journal of chemical …, 1997 - pubs.aip.org
We consider here a polymer blend made of two crosslinked polymers A and B of different
chemical nature, in the presence of a common solvent assumed to be good for both species …
chemical nature, in the presence of a common solvent assumed to be good for both species …
Glassy correlations and microstructures in randomly cross-linked homopolymer blends
C Wald, PM Goldbart, A Zippelius - The Journal of chemical physics, 2006 - pubs.aip.org
We consider a microscopic model of a polymer blend that is prone to phase separation.
Permanent cross-links are introduced between randomly chosen pairs of monomers, drawn …
Permanent cross-links are introduced between randomly chosen pairs of monomers, drawn …