Abstract The importance of 1, 5‐O⋅⋅⋅ chalcogen (Ch) interactions in isochalcogenourea
catalysis (Ch= O, S, Se) is investigated. Conformational analyses of N‐acyl …

N-Heterocyclic carbenes (NHCs) are now well-established organocatalysts for a large
number of asymmetric and non-asymmetric transformations. In the last 15 years, there has …

Herein, we report a cobalt-catalyzed atroposelective reductive cross-coupling of racemic
heterobiaryl tosylates with a C (sp2)–X type electrophile. Both aryl and alkenyl halides are …

Conspectus Asymmetric cation-binding catalysis in principle enables the use of (alkali)
metal salts, otherwise insoluble in organic solvents, as reagents and effectors in …

The catalytic asymmetric synthesis of P‐chiral phosphorus compounds is an important way
to construct P‐chiral ligands. Herein, we report a new strategy that adopts the pyridinyl …

A general and mild nickel‐catalyzed enantioselective C (sp2)− P cross‐coupling for
synthesizing P‐stereogenic phosphine oxides has been developed. The asymmetric …

Herein we report a Pd‐catalyzed asymmetric allenylic alkylation strategy for the direct
functionalization of 1H‐indoles by employing P‐chiral BIBOP‐type ligands. The …

Chiral NHC-catalyzed kinetic resolution of N-aryl aminomaleimides allowing the synthesis of
C–N axially chiral N-aryl aminomaleimides via remote chirality control is presented. The …

The synthesis of P-stereogenic building blocks is extremely difficult. Herein we report an
efficient kinetic resolution of secondary phosphine oxides via a Le-Phos-catalyzed …

Herein we present an efficient chiral phosphoric-acid-catalyzed atropoenantioselective
asymmetric reductive amination of biaryl dialdehydes. The process involves …