Femtosecond electron diffraction: heralding the era of atomically resolved dynamics

G Sciaini, RJD Miller - Reports on Progress in Physics, 2011 - iopscience.iop.org
One of the great dream experiments in Science is to directly observe atomic motions as they
occur. Femtosecond electron diffraction provided the first'light'of sufficient intensity to …

4D ultrafast electron diffraction, crystallography, and microscopy

AH Zewail - Annu. Rev. Phys. Chem., 2006 - annualreviews.org
▪ Abstract In this review, we highlight the progress made in the development of 4D ultrafast
electron diffraction (UED), crystallography (UEC), and microscopy (UEM) with a focus on …

An atomic-level view of melting using femtosecond electron diffraction

BJ Siwick, JR Dwyer, RE Jordan, RJD Miller - Science, 2003 - science.org
We used 600-femtosecond electron pulses to study the structural evolution of aluminum as it
underwent an ultrafast laser–induced solid-liquid phase transition. Real-time observations …

The photochemical ring-opening of 1, 3-cyclohexadiene imaged by ultrafast electron diffraction

TJA Wolf, DM Sanchez, J Yang, RM Parrish… - Nature …, 2019 - nature.com
The ultrafast photoinduced ring-opening of 1, 3-cyclohexadiene constitutes a textbook
example of electrocyclic reactions in organic chemistry and a model for photobiological …

Simultaneous observation of nuclear and electronic dynamics by ultrafast electron diffraction

J Yang, X Zhu, JP F. Nunes, JK Yu, RM Parrish… - Science, 2020 - science.org
Simultaneous observation of nuclear and electronic motion is crucial for a complete
understanding of molecular dynamics in excited electronic states. It is challenging for a …

Femtosecond crystallography with ultrabright electrons and x-rays: Capturing chemistry in action

RJD Miller - Science, 2014 - science.org
With the recent advances in ultrabright electron and x-ray sources, it is now possible to
extend crystallography to the femtosecond time domain to literally light up atomic motions …

Ultrafast electron microscopy in materials science, biology, and chemistry

WE King, GH Campbell, A Frank, B Reed… - Journal of Applied …, 2005 - pubs.aip.org
The use of pump-probe experiments to study complex transient events has been an area of
significant interest in materials science, biology, and chemistry. While the emphasis has …

Imaging molecular motion: femtosecond x-ray scattering of an electrocyclic chemical reaction

MP Minitti, JM Budarz, A Kirrander, JS Robinson… - Physical review …, 2015 - APS
Structural rearrangements within single molecules occur on ultrafast time scales. Many
aspects of molecular dynamics, such as the energy flow through excited states, have been …

Capturing chemistry in action with electrons: realization of atomically resolved reaction dynamics

AA Ischenko, PM Weber, RJD Miller - Chemical reviews, 2017 - ACS Publications
One of the grand challenges in chemistry has been to directly observe atomic motions
during chemical processes. The depiction of the nuclear configurations in space-time to …

Ultrafast electron diffraction (UED) a new development for the 4D determination of transient molecular structures

R Srinivasan, VA Lobastov, CY Ruan… - Helvetica chimica …, 2003 - Wiley Online Library
With properly timed sequences of ultrafast electron pulses, it is now possible to image
complex molecular structures in the four dimensions of space and time with resolutions of …