Optical phenomena in molecule-based magnetic materials

JJ Zakrzewski, M Liberka, J Wang, S Chorazy… - Chemical …, 2024 - ACS Publications
Since the last century, we have witnessed the development of molecular magnetism which
deals with magnetic materials based on molecular species, ie, organic radicals and metal …

Detour to success: photoswitching via indirect excitation

K Kuntze, J Isokuortti, JJ van der Wal, T Laaksonen… - Chemical …, 2024 - pubs.rsc.org
Photoswitchable molecules that undergo nanoscopic changes upon photoisomerisation can
be harnessed to control macroscopic properties such as colour, solubility, shape, and …

Red-light photoswitching of indigos in polymer thin films

K Kuntze, J Viljakka, M Virkki, CYD Huang, S Hecht… - Chemical …, 2023 - pubs.rsc.org
Through simple synthetic derivatisation, the parent indigo dye becomes a red-light E–Z
photoswitch exhibiting negative photochromism and tuneable thermal isomerisation kinetics …

Light‐Switchable Metal Complexes: Introducing Photoresponsive Behaviour Through Azoheteroarenes

D Gupta, AK Gaur, H Kumar, S Singh… - …, 2023 - Wiley Online Library
Azoheteroarenes are emerging classes of photoswitches with versatile scaffolds that offer
distinct features such as efficient photoisomerization, tunable stability of the photoswitched …

Photoisomerization of 2-arylazoimidazoles under visible light: identifying a predictive tool to anticipate and tune likely photoswitching performance and cis half-life

A Dolai, SM Box, S Bhunia, S Bera, A Das… - The Journal of …, 2023 - ACS Publications
Azopyrazoles are an emerging class of photoswitches, whereas analogous azoimidazole-
based switches are unable to draw much attention because of their short cis half-lives, poor …

Photo‐SABRE: Nuclear Spin Hyperpolarization of cis‐trans Photoswitchable Molecules by Parahydrogen**

AS Kiryutin, VP Kozinenko… - ChemPhotoChem, 2024 - Wiley Online Library
This work reports the 23000‐and 9200‐fold enhancement of the 15N nuclear spin
polarization of cis and trans isomers of azobenzene, correspondingly, as compared to the …

Azobenzene‐Based Conjugated Polymers: Synthesis, Properties, and Biological Applications

Z Ma, J Wu, Y Tan, C Tan - Macromolecular Rapid …, 2024 - Wiley Online Library
Conjugated polymers (CPs) have been developed quickly as an emerging functional
material with applications in optical and electronic devices, owing to their highly electron …

Twelve-membered ring photoswitches with excellent Z→ E conversion under ambient light

R Falkenburg, MJ Notheis, G Schnakenburg… - Organic & …, 2023 - pubs.rsc.org
Incorporation of azobenzenes into macrocycles is an intriguing approach for fine tuning the
photophysical properties of these photoswitches and tailoring them to specific applications …

Red-shifted and pH-responsive imidazole-based azo dyes with potent antimicrobial activity

D Dantas, AI Ribeiro, F Carvalho… - Chemical …, 2023 - pubs.rsc.org
A novel route is described to obtain 2—aminoimidazole azo dyes with a unique substituent
pattern in the heteroaryl unit that provides halochromic properties, exhibiting vibrant colours …

Photoswitchable Azoheteroarene‐Based Chelating Ligands: Light Modulation of Properties, Aqueous Solubility and Catalysis

D Gupta, AK Gaur, R Kaur, Ashish… - … A European Journal, 2023 - Wiley Online Library
We report the design and synthesis of eight photoswitchable phenylazopyridine‐and
phenylazopyrazole‐based molecular systems as chelation‐type light‐controllable ligands …