[HTML][HTML] Regioisomeric effect of heteroatoms and functional groups of organic ligands: impacts on coordination bonding and corrosion protection performance

C Verma, A Singh, P Singh, KY Rhee… - Coordination Chemistry …, 2024 - Elsevier
The regioisomeric effect, which refers to the different positions of heteroatoms and functional
groups on a molecule, significantly impacts the stability, physicochemical properties …

Photochemistry driven by excited‐state aromaticity gain or antiaromaticity relief

J Yan, T Slanina, J Bergman… - Chemistry–A European …, 2023 - Wiley Online Library
Gain of aromaticity or relief of antiaromaticity along a reaction path are important factors to
consider in mechanism studies. Analysis of such changes along potential energy surfaces …

Ultra-photostable small-molecule dyes facilitate near-infrared biophotonics

K Yan, Z Hu, P Yu, Z He, Y Chen, J Chen, H Sun… - Nature …, 2024 - nature.com
Long-wavelength, near-infrared small-molecule dyes are attractive in biophotonics.
Conventionally, they rely on expanded aromatic structures for redshift, which comes at the …

Single‐Benzene Dual‐Emitters Harness Excited‐State Antiaromaticity for White Light Generation and Fluorescence Imaging

Y Kim, H Kim, JB Son, M Filatov… - Angewandte Chemie …, 2023 - Wiley Online Library
Molecular emitters simultaneously generating light at different wavelengths have wide
applications. With a small molecule, however, it is challenging to realize two independent …

Electronic Tuning in Reaction‐Based Fluorescent Sensing for Instantaneous and Ultrasensitive Visualization of Ethylenediamine

Y Ke, Y Liu, B Zu, D Lei, G Wang, J Li… - Angewandte Chemie …, 2022 - Wiley Online Library
Manipulation of a multi‐physical quantity to steer a molecular photophysical property is of
great significance in improving sensing performance. Here, an investigation on how a …

Small is beautiful: electronic origin and synthetic evolution of single-benzene fluorophores

H Kim, Y Kim, D Lee - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Single-benzene fluorophores (SBFs) are small molecules that produce visible
light by using only one benzene ring as the sole aromatic core. This Account centers around …

Janus‐type ESIPT chromophores with distinctive intramolecular hydrogen‐bonding selectivity

Y Chen, S Lu, SA Abbas Abedi, M Jeong… - Angewandte Chemie …, 2023 - Wiley Online Library
Excited‐state intramolecular proton transfer (ESIPT)‐based solid luminescent materials with
multiple hydrogen bond acceptors (HBAs) remain unexplored. Herein, we introduced a …

[HTML][HTML] Recent advances in minimal fluorescent probes for optical imaging

F De Moliner, F Nadal-Bufi, M Vendrell - Current opinion in chemical …, 2024 - Elsevier
Fluorescent probes have revolutionized biological imaging by enabling the real-time
visualization of cellular processes under physiological conditions. However, their size and …

Baird's rules at the tip** point

LJ Karas, JI Wu - Nature chemistry, 2022 - nature.com
Baird’s rules at the tip** point | Nature Chemistry Skip to main content Thank you for visiting
nature.com. You are using a browser version with limited support for CSS. To obtain the best …

Dithienoazepine‐Based Near‐Infrared Dyes: Janus‐Faced Effects of a Thiophene‐Fused Structure on Antiaromatic Azepines

M Murai, T Enoki, S Yamaguchi - … Chemie International Edition, 2023 - Wiley Online Library
We here disclose that the incorporation of thiophene rings into a seven‐membered 8π
azepine in a fused fashion produces a useful antiaromatic core for near‐infrared (NIR) dyes …