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[HTML][HTML] Regioisomeric effect of heteroatoms and functional groups of organic ligands: impacts on coordination bonding and corrosion protection performance
The regioisomeric effect, which refers to the different positions of heteroatoms and functional
groups on a molecule, significantly impacts the stability, physicochemical properties …
groups on a molecule, significantly impacts the stability, physicochemical properties …
Photochemistry driven by excited‐state aromaticity gain or antiaromaticity relief
Gain of aromaticity or relief of antiaromaticity along a reaction path are important factors to
consider in mechanism studies. Analysis of such changes along potential energy surfaces …
consider in mechanism studies. Analysis of such changes along potential energy surfaces …
Ultra-photostable small-molecule dyes facilitate near-infrared biophotonics
Long-wavelength, near-infrared small-molecule dyes are attractive in biophotonics.
Conventionally, they rely on expanded aromatic structures for redshift, which comes at the …
Conventionally, they rely on expanded aromatic structures for redshift, which comes at the …
Single‐Benzene Dual‐Emitters Harness Excited‐State Antiaromaticity for White Light Generation and Fluorescence Imaging
Molecular emitters simultaneously generating light at different wavelengths have wide
applications. With a small molecule, however, it is challenging to realize two independent …
applications. With a small molecule, however, it is challenging to realize two independent …
Electronic Tuning in Reaction‐Based Fluorescent Sensing for Instantaneous and Ultrasensitive Visualization of Ethylenediamine
Y Ke, Y Liu, B Zu, D Lei, G Wang, J Li… - Angewandte Chemie …, 2022 - Wiley Online Library
Manipulation of a multi‐physical quantity to steer a molecular photophysical property is of
great significance in improving sensing performance. Here, an investigation on how a …
great significance in improving sensing performance. Here, an investigation on how a …
Small is beautiful: electronic origin and synthetic evolution of single-benzene fluorophores
H Kim, Y Kim, D Lee - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Single-benzene fluorophores (SBFs) are small molecules that produce visible
light by using only one benzene ring as the sole aromatic core. This Account centers around …
light by using only one benzene ring as the sole aromatic core. This Account centers around …
Janus‐type ESIPT chromophores with distinctive intramolecular hydrogen‐bonding selectivity
Excited‐state intramolecular proton transfer (ESIPT)‐based solid luminescent materials with
multiple hydrogen bond acceptors (HBAs) remain unexplored. Herein, we introduced a …
multiple hydrogen bond acceptors (HBAs) remain unexplored. Herein, we introduced a …
[HTML][HTML] Recent advances in minimal fluorescent probes for optical imaging
Fluorescent probes have revolutionized biological imaging by enabling the real-time
visualization of cellular processes under physiological conditions. However, their size and …
visualization of cellular processes under physiological conditions. However, their size and …
Baird's rules at the tip** point
Baird’s rules at the tip** point | Nature Chemistry Skip to main content Thank you for visiting
nature.com. You are using a browser version with limited support for CSS. To obtain the best …
nature.com. You are using a browser version with limited support for CSS. To obtain the best …
Dithienoazepine‐Based Near‐Infrared Dyes: Janus‐Faced Effects of a Thiophene‐Fused Structure on Antiaromatic Azepines
M Murai, T Enoki, S Yamaguchi - … Chemie International Edition, 2023 - Wiley Online Library
We here disclose that the incorporation of thiophene rings into a seven‐membered 8π
azepine in a fused fashion produces a useful antiaromatic core for near‐infrared (NIR) dyes …
azepine in a fused fashion produces a useful antiaromatic core for near‐infrared (NIR) dyes …