Spinel-type persistent luminescence nanoparticles: From mechanisms, compositions to applications

T Zhao, R Abdurahman, R Aiwaili, S Wu… - Coordination Chemistry …, 2023 - Elsevier
Spinel-structure persistent luminescence nanoparticles (SS-PLNPs) have attracted
considerable interest due to their magical afterglow emission. SS-PLNPs constitute spinel …

Unraveling a concerted proton-coupled electron transfer pathway in atomically precise gold nanoclusters

KY Huang, ZQ Yang, MR Yang, TS Chen… - Journal of the …, 2024 - ACS Publications
Metal nanoclusters (MNCs) represent a promising class of materials for catalytic carbon
dioxide and proton reduction as well as dihydrogen oxidation. In such reactions, multiple …

Exploring proton-coupled electron transfer at multiple scales

S Hammes-Schiffer - Nature computational science, 2023 - nature.com
The coupling of electron and proton transfer is critical for chemical and biological processes
spanning a wide range of length and time scales and often occurring in complex …

Symmetry-breaking dynamics in a tautomeric 3D covalent organic framework

Y Xu, T Sun, T Zeng, X Zhang, X Yao, S Liu… - Nature …, 2023 - nature.com
The enolimine-ketoenamine tautomerism has been utilised to construct 2D covalent organic
frameworks (COFs) with a higher level of chemical robustness and superior photoelectronic …

Facilitating proton-coupled electron transfer for energy-efficient CO2 desorption by C@ ZrO2 hollow composites

Y Shen, K Wang, L Li, J Zhao, J Ye, P Chen… - Chemical Engineering …, 2024 - Elsevier
Catalyst-aided CO 2 desorption offers a promising reduction in the energy penalty of amine
scrubbing, but faces the challenges of slow mass transfer, sluggish desorption kinetics, and …

Visible-light-activated carbon monoxide release from porphyrin–flavonol hybrids

A Ramundo, J Janoš, L Muchová… - Journal of the …, 2023 - ACS Publications
We report on porphyrin–flavonol hybrids consisting of a porphyrin antenna and four
covalently bound 3-hydroxyflavone (flavonol) groups, which act as highly efficient …

Sequential Multistep Excited‐State Structural Transformations in N,N′‐Diphenyl‐dihydrodibenzo[a,c]phenazine Fluorophores

X **, S Guo, X Wang, M Cong, J Chen… - Angewandte …, 2023 - Wiley Online Library
We demonstrate that a single polycyclic π‐scaffold can undergo sequential multistep excited‐
state structural evolution along the bent, planar, and twisted conformers, which coexist to …

Facilitating Proton Coupled Electron Transfer Reaction through the Interfacial Micro Electric Field with Fe─N4─C in FeMOFs Glass

S Zuo, Y Wang, J Wan, Y Ma, Z Yan - Small, 2024 - Wiley Online Library
The proton‐coupled electron transfer (PCET) reaction plays a crucial role in the chemical
transformation process andhas become one of the most concerned elementary reactions …

Cationized orthogonal triad as a photosensitizer with enhanced synergistic antimicrobial activity

X Hao, Y Tang, R Zhang, Z Wang, M Gao, R Wei… - Acta Biomaterialia, 2024 - Elsevier
Single-molecule-based synergistic phototherapy holds great potential for antimicrobial
treatment. Herein, we report an orthogonal molecular cationization strategy to improve the …

Reorganization energies for interfacial proton-coupled electron transfer to a water oxidation catalyst

M Kessinger, AV Soudackov, J Schneider… - Journal of the …, 2022 - ACS Publications
The reorganization energy (λ) for interfacial electron transfer (ET) and proton-coupled ET
(PCET) from a conductive metal oxide (In2O3: Sn, ITO) to a surface-bound water oxidation …