H2 and carbon-heteroatom bond activation mediated by polarized heterobimetallic complexes

RM Charles III, TP Brewster - Coordination chemistry reviews, 2021 - Elsevier
The field of heterobimetallic chemistry has rapidly expanded over the last decade. In
addition to their interesting structural features, heterobimetallic structures have been found …

Anion chelation via double chalcogen bonding: The case of a bis-telluronium dication and its application in electrophilic catalysis via metal–chloride bond activation

B Zhou, FP Gabbaï - Journal of the American Chemical Society, 2021 - ACS Publications
Telluronium cations have long been known to engage their counteranions via secondary
interactions. Yet, this property has rarely been exploited for anion binding. Motivated by such …

Investigation of Ketone C O Bond Activation Processes by Heterobimetallic Zr/Co and Ti/Co Tris (phosphinoamide) Complexes

H Zhang, B Wu, SL Marquard, ED Litle… - …, 2017 - ACS Publications
The reactivity of the reduced Zr/Co and Ti/Co complexes (THF) Zr (MesNP i Pr2) 3CoN2 (1,
Mes= 2, 4, 6-trimethylphenyl) and (THF) Ti (XylNP i Pr2) 3CoN2 (7, Xyl= 3, 5 …

Heterobimetallic Complexes Comprised of Nb and Fe: Isolation of a Coordinatively Unsaturated NbIII/Fe0 Bimetallic Complex Featuring a NbFe Triple Bond

G Culcu, DA Iovan, JP Krogman… - Journal of the …, 2017 - ACS Publications
Heterometallic multiple bonds between niobium and other transition metals have not been
reported to date, likely owing to the highly reactive nature of low-valent niobium centers …

The chemistry of the carbon-transition metal double and triple bond: annual survey covering the year 2016

JW Herndon - Coordination Chemistry Reviews, 2018 - Elsevier
This is a review of papers published in the year 2016 that focus on the synthesis, reactivity,
or properties of compounds containing a carbon-transition metal double or triple bond …

An Electrophilic, Intramolecularly Base-Stabilized Platinum–Antimony Complex

JE Smith, H Yang, FP Gabbaï - Organometallics, 2021 - ACS Publications
As part of our interest in the chemistry of late transition metal complexes bearing cationic
antimony ligands, we have investigated the reaction of ((o-(Ph2P) C6H4) 3) SbClPtCl (1) …

Evaluation of Pd→ B Interactions in Diphosphinoborane Complexes and Impact on Inner‐Sphere Reductive Elimination

F Ritter, L John, T Schindler… - … A European Journal, 2020 - Wiley Online Library
Abstract The dative Pd→ B interaction in a series of RDPBR'Pd0 and PdII complexes
(RDPBR'=(o‐PR2C6H4) 2BR', diphosphinoborane) was analyzed using XRD, 11B NMR …

Structural Evidence for Pnictogen-Centered Lewis Acidity in Cationic Platinum-Stibine Complexes Featuring Pendent Amino or Ammonium Groups

RR Rodrigues, FP Gabbaï - Molecules, 2021 - mdpi.com
As part of our continuing interest in the chemistry of cationic antimony Lewis acids as ligands
for late transition metals, we have now investigated the synthesis of platinum complexes …

Chalcogen‐Bonding Catalyzed In Situ Trityl Cation Activation for C—C Bond Forming Reactions

N Lohmann, K Fengler, AC Keuper… - …, 2024 - Wiley Online Library
In this work, the use of chalcogen bonding for the catalytic activation of trityl cation by
chloride abstraction from bench stable trityl chloride and further application in C—C bond …

Synthesis and characterization of triply-bonded titanium-iron complexes supported by 2-(diphenylphosphino) pyrrolide ligands

PL Dunn, RK Carlson, IA Tonks - Inorganica Chimica Acta, 2017 - Elsevier
The synthesis of several titanium-iron multiply bonded complexes supported by a 2-
(diphenylphosphino) pyrrolide (NP) ligand is reported. Treatment of the homoleptic, 8 …