Cobalt‐free cathode materials: families and their prospects

H Zhao, WYA Lam, L Sheng, L Wang… - Advanced Energy …, 2022 - Wiley Online Library
With the rapid growth of global electro‐mobility, the demand for cobalt is rapidly increasing
because it is currently an indispensable component of the cathode materials in lithium‐ion …

Pushing the limit of 3d transition metal-based layered oxides that use both cation and anion redox for energy storage

M Zhang, DA Kitchaev, Z Lebens-Higgins… - Nature Reviews …, 2022 - nature.com
Intercalation chemistry has dominated electrochemical energy storage for decades, and
storage capacity worldwide has now reached the terawatt-hour level. State-of-the-art …

First-cycle voltage hysteresis in Li-rich 3d cathodes associated with molecular O2 trapped in the bulk

RA House, GJ Rees, MA Pérez-Osorio, JJ Marie… - Nature Energy, 2020 - nature.com
Li-rich cathode materials are potential candidates for next-generation Li-ion batteries.
However, they exhibit a large voltage hysteresis on the first charge/discharge cycle, which …

The role of O2 in O-redox cathodes for Li-ion batteries

RA House, JJ Marie, MA Pérez-Osorio, GJ Rees… - Nature Energy, 2021 - nature.com
The energy density of Li-ion batteries can be improved by storing charge at high voltages
through the oxidation of oxide ions in the cathode material. However, oxidation of O2 …

Unraveling anionic redox for sodium layered oxide cathodes: breakthroughs and perspectives

H Ren, Y Li, Q Ni, Y Bai, H Zhao, C Wu - Advanced Materials, 2022 - Wiley Online Library
Sodium‐ion batteries (SIBs) as the next generation of sustainable energy technologies have
received widespread investigations for large‐scale energy storage systems (EESs) and …

Unveiling the Evolution of LiCoO2 beyond 4.6 V

Z Wu, G Zeng, J Yin, CL Chiang, Q Zhang… - ACS Energy …, 2023 - ACS Publications
The working mechanism of LiCoO2 beyond 4.6 V presents complicated issues:(1) the
ambiguous multistructural evolutions,(2) the vague O-related anionic redox reactions (ARR) …

Revealing lithium battery gas generation for safer practical applications

P Liu, L Yang, B **ao, H Wang, L Li… - Advanced Functional …, 2022 - Wiley Online Library
Gases generated from lithium batteries are detrimental to their electrochemical
performances, especially under the unguarded runaway conditions, which tend to contribute …

In Situ Gas Analysis by Differential Electrochemical Mass Spectrometry for Advanced Rechargeable Batteries: A Review

S Kim, HS Kim, B Kim, YJ Kim… - Advanced Energy …, 2023 - Wiley Online Library
Lithium‐ion batteries (LIBs) and beyond‐LIB systems exhibit properties that are determined
by electrochemical reactions occurring in their four essential components—the cathode …

Building better full manganese-based cathode materials for next-generation lithium-ion batteries

J Song, H Wang, Y Zuo, K Zhang, T Yang… - Electrochemical Energy …, 2023 - Springer
Lithium-manganese-oxides have been exploited as promising cathode materials for many
years due to their environmental friendliness, resource abundance and low biotoxicity …

Cycling mechanism of Li2MnO3: Li–CO2 batteries and commonality on oxygen redox in cathode materials

Z Zhuo, K Dai, R Qiao, R Wang, J Wu, Y Liu, J Peng… - Joule, 2021 - cell.com
Li 2 MnO 3 has been considered to be a representative Li-rich compound with active
debates on oxygen activities. Here, by evaluating the Mn and O states in the bulk and on the …