Explicitly correlated electrons in molecules

C Hattig, W Klopper, A Kohn, DP Tew - Chemical reviews, 2012 - ACS Publications
One of the central challenges of computational molecular investigation is the solution of the
time-independent, nonrelativistic BornÀ Oppenheimer electronic Schrödinger equation. For …

Theory and application of explicitly correlated Gaussians

J Mitroy, S Bubin, W Horiuchi, Y Suzuki… - Reviews of modern …, 2013 - APS
The variational method complemented with the use of explicitly correlated Gaussian basis
functions is one of the most powerful approaches currently used for calculating the …

Quantum electrodynamics effects in rovibrational spectra of molecular hydrogen

J Komasa, K Piszczatowski, G Łach… - Journal of chemical …, 2011 - ACS Publications
The dissociation energies from all rovibrational levels of H2 and D2 in the ground electronic
state are calculated with high accuracy by including relativistic and quantum …

Rovibrational energy levels of the hydrogen molecule through nonadiabatic perturbation theory

J Komasa, M Puchalski, P Czachorowski, G Łach… - Physical Review A, 2019 - APS
We present an accurate theoretical determination of rovibrational energy levels of the
hydrogen molecule and its isotopologues in its electronic ground state. We consider all …

Bounds on fifth forces from precision measurements on molecules

EJ Salumbides, JCJ Koelemeij, J Komasa… - Physical Review D …, 2013 - APS
Highly accurate results from frequency measurements on neutral hydrogen molecules H 2,
HD, and D 2 as well as the HD+ ion can be interpreted in terms of constraints on possible …

Fundamental vibration of molecular hydrogen

GD Dickenson, ML Niu, EJ Salumbides, J Komasa… - Physical review …, 2013 - APS
The fundamental ground tone vibration of H 2, HD, and D 2 is determined to an accuracy
of<? format?> 2× 10-4 cm-1 from Doppler-free laser spectroscopy in the collisionless …

Born–Oppenheimer and non-Born–Oppenheimer, atomic and molecular calculations with explicitly correlated Gaussians

S Bubin, M Pavanello, WC Tung, KL Sharkey… - Chemical …, 2013 - ACS Publications
Since the early work of Hylleraas on the helium atom, 1 it has been common knowledge that,
to accurately account for the interaction between the electrons in an atom or a molecule …

[HTML][HTML] Physics beyond the Standard Model from hydrogen spectroscopy

W Ubachs, JCJ Koelemeij, KSE Eikema… - Journal of Molecular …, 2016 - Elsevier
Spectroscopy of hydrogen can be used for a search into physics beyond the Standard
Model. Differences between the absorption spectra of the Lyman and Werner bands of H 2 …

The full infrared spectrum of molecular hydrogen

E Roueff, H Abgrall, P Czachorowski… - Astronomy & …, 2019 - aanda.org
Context. The high spectral resolution R∼ 45 000 provided by IGRINS (Immersion Grating
INfrared Spectrometer) at MacDonald Observatory and R∼ 100 000 achieved by CRIRES …

Improved ionization and dissociation energies of the deuterium molecule

J Hussels, N Hölsch, CF Cheng, EJ Salumbides… - Physical Review A, 2022 - APS
The ionization energy of D 2 has been determined experimentally from measurements
involving two-photon Doppler-free vacuum-ultraviolet pulsed laser excitation and near …