Covalent mechanochemistry and contemporary polymer network chemistry: a marriage in the making

EM Lloyd, JR Vakil, Y Yao, NR Sottos… - Journal of the American …, 2023 - ACS Publications
Over the past 20 years, the field of polymer mechanochemistry has amassed a toolbox of
mechanophores that translate mechanical energy into a variety of functional responses …

Mechanochemical degradation and recycling of synthetic polymers

J Zhou, TG Hsu, J Wang - Angewandte Chemie, 2023 - Wiley Online Library
The accumulation of plastic waste, due to lack of recycling, has led to serious environmental
pollution. Although mechanical recycling can alleviate this issue, it inevitably reduces the …

Polymer mechanochromism from force-tuned excited-state intramolecular proton transfer

H Hu, X Cheng, Z Ma, RP Sijbesma… - Journal of the American …, 2022 - ACS Publications
Real-time monitoring of strain/stress in polymers is a big challenge to date. Herein, we for
the first time report an ESIPT (excited-state intramolecular proton transfer)-based …

Harnessing the power of force: development of mechanophores for molecular release

BA Versaw, T Zeng, X Hu, MJ Robb - Journal of the American …, 2021 - ACS Publications
Polymers that release small molecules in response to mechanical force are promising
materials for a variety of applications ranging from sensing and catalysis to targeted drug …

Recent advances in the development of phenothiazine and its fluorescent derivatives for optoelectronic applications

F Khan, R Misra - Journal of Materials Chemistry C, 2023 - pubs.rsc.org
Phenothiazine is one of the most extensively investigated aromatic compounds owing to its
unique optical and electronic properties, low cost, and easy functionalization. In recent …

Ratiometric flap** force probe that works in polymer gels

T Yamakado, S Saito - Journal of the American Chemical Society, 2022 - ACS Publications
Polymer gels have recently attracted attention for their application in flexible devices, where
mechanically robust gels are required. While there are many strategies to produce tough …

Stimuli-responsive structure–property switchable polymer materials

ZM Png, CG Wang, JCC Yeo, JJC Lee… - … Systems Design & …, 2023 - pubs.rsc.org
The development of polymeric materials with switchable properties upon exposure to
external stimuli such as light, heat, force, acids/bases, and chemicals has attracted much …

Rotaxane-based dual function mechanophores exhibiting reversible and irreversible responses

T Muramatsu, Y Okado, H Traeger… - Journal of the …, 2021 - ACS Publications
Mechanochromic mechanophores permit the design of polymers that indicate mechanical
events through optical signals. Here we report rotaxane-based supramolecular …

Cooperative and geometry-dependent mechanochromic reactivity through aromatic fusion of two rhodamines in polymers

M Wu, Y Li, W Yuan, G De Bo, Y Cao… - Journal of the American …, 2022 - ACS Publications
The unique topological features of Piezo proteins underlie the lever-like cellular
mechanotransduction mechanism. This knowledge inspires us to seek topological/geometric …

Conformer Ring Flip Enhances Mechanochromic Performance of ansa-Donor–Acceptor–Donor Mechanochromic Torsional Springs

R Hertel, W Maftuhin, M Walter… - Journal of the American …, 2022 - ACS Publications
Mechanochromophores based on conformational changes of donor–acceptor–donor (DAD)
springs allow sensing of forces acting on polymer chains by monotonic changes of …