Covalent mechanochemistry and contemporary polymer network chemistry: a marriage in the making
Over the past 20 years, the field of polymer mechanochemistry has amassed a toolbox of
mechanophores that translate mechanical energy into a variety of functional responses …
mechanophores that translate mechanical energy into a variety of functional responses …
Mechanochemical degradation and recycling of synthetic polymers
The accumulation of plastic waste, due to lack of recycling, has led to serious environmental
pollution. Although mechanical recycling can alleviate this issue, it inevitably reduces the …
pollution. Although mechanical recycling can alleviate this issue, it inevitably reduces the …
Polymer mechanochromism from force-tuned excited-state intramolecular proton transfer
Real-time monitoring of strain/stress in polymers is a big challenge to date. Herein, we for
the first time report an ESIPT (excited-state intramolecular proton transfer)-based …
the first time report an ESIPT (excited-state intramolecular proton transfer)-based …
Harnessing the power of force: development of mechanophores for molecular release
Polymers that release small molecules in response to mechanical force are promising
materials for a variety of applications ranging from sensing and catalysis to targeted drug …
materials for a variety of applications ranging from sensing and catalysis to targeted drug …
Recent advances in the development of phenothiazine and its fluorescent derivatives for optoelectronic applications
Phenothiazine is one of the most extensively investigated aromatic compounds owing to its
unique optical and electronic properties, low cost, and easy functionalization. In recent …
unique optical and electronic properties, low cost, and easy functionalization. In recent …
Ratiometric flap** force probe that works in polymer gels
T Yamakado, S Saito - Journal of the American Chemical Society, 2022 - ACS Publications
Polymer gels have recently attracted attention for their application in flexible devices, where
mechanically robust gels are required. While there are many strategies to produce tough …
mechanically robust gels are required. While there are many strategies to produce tough …
Stimuli-responsive structure–property switchable polymer materials
The development of polymeric materials with switchable properties upon exposure to
external stimuli such as light, heat, force, acids/bases, and chemicals has attracted much …
external stimuli such as light, heat, force, acids/bases, and chemicals has attracted much …
Rotaxane-based dual function mechanophores exhibiting reversible and irreversible responses
T Muramatsu, Y Okado, H Traeger… - Journal of the …, 2021 - ACS Publications
Mechanochromic mechanophores permit the design of polymers that indicate mechanical
events through optical signals. Here we report rotaxane-based supramolecular …
events through optical signals. Here we report rotaxane-based supramolecular …
Cooperative and geometry-dependent mechanochromic reactivity through aromatic fusion of two rhodamines in polymers
The unique topological features of Piezo proteins underlie the lever-like cellular
mechanotransduction mechanism. This knowledge inspires us to seek topological/geometric …
mechanotransduction mechanism. This knowledge inspires us to seek topological/geometric …
Conformer Ring Flip Enhances Mechanochromic Performance of ansa-Donor–Acceptor–Donor Mechanochromic Torsional Springs
Mechanochromophores based on conformational changes of donor–acceptor–donor (DAD)
springs allow sensing of forces acting on polymer chains by monotonic changes of …
springs allow sensing of forces acting on polymer chains by monotonic changes of …