Comb and bottlebrush polymers with superior rheological and mechanical properties
M Abbasi, L Faust, M Wilhelm - Advanced Materials, 2019 - Wiley Online Library
Comb and bottlebrush polymers present a wide range of rheological and mechanical
properties that can be controlled through their molecular characteristics, such as the …
properties that can be controlled through their molecular characteristics, such as the …
Morphological/nanostructural control toward intrinsically stretchable organic electronics
The development of intrinsically stretchable electronics poses great challenges in
synthesizing elastomeric conductors, semiconductors and dielectric materials. While a wide …
synthesizing elastomeric conductors, semiconductors and dielectric materials. While a wide …
Solvent-free, supersoft and superelastic bottlebrush melts and networks
Polymer gels are the only viable class of synthetic materials with a Young's modulus below
100 kPa conforming to biological applications,,, yet those gel properties require a solvent …
100 kPa conforming to biological applications,,, yet those gel properties require a solvent …
Property-guided generation of complex polymer topologies using variational autoencoders
The complexity and diversity of polymer topologies, or chain architectures, present
substantial challenges in predicting and engineering polymer properties. Although machine …
substantial challenges in predicting and engineering polymer properties. Although machine …
Combs and Bottlebrushes in a Melt
We use a combination of the coarse-grained molecular dynamics simulations and scaling
analysis to study conformations of bottlebrush and comb-like polymers in a melt. Our …
analysis to study conformations of bottlebrush and comb-like polymers in a melt. Our …
Synthesis of high molecular weight comb block copolymers and their assembly into ordered morphologies in the solid state
MB Runge, NB Bowden - Journal of the American Chemical …, 2007 - ACS Publications
This Article describes a simple two-step synthesis of comb block copolymers with molecular
weights exceeding 1 000 000 g mol-1 and their assembly into ordered morphologies in the …
weights exceeding 1 000 000 g mol-1 and their assembly into ordered morphologies in the …
Linear and extensional rheology of model branched polystyrenes: From loosely grafted combs to bottlebrushes
M Abbasi, L Faust, K Riazi, M Wilhelm - Macromolecules, 2017 - ACS Publications
Monodisperse comb polystyrenes (comb-PS) with loosely to densely grafted architectures
up to loosely grafted bottlebrush structures were synthesized via anionic polymerization …
up to loosely grafted bottlebrush structures were synthesized via anionic polymerization …
Linking models of polymerization and dynamics to predict branched polymer structure and flow
We present a predictive scheme connecting the topological structure of highly branched
entangled polymers, with industrial-level complexity, to the emergent viscoelasticity of the …
entangled polymers, with industrial-level complexity, to the emergent viscoelasticity of the …
Rheological and mechanical study of comb-branched polyolefin elastomers containing macromer residues
Comb-polyolefin elastomers (CPOEs) with crystalline long-chain branches (LCBes)
demonstrate superior mechanical properties and processability. However, fully …
demonstrate superior mechanical properties and processability. However, fully …
A critical approach to polymer dynamics in supramolecular polymers
Over the past few years, the concurrent (1) development of polymer synthesis and (2)
introduction of new mathematical models for polymer dynamics have evolved the classical …
introduction of new mathematical models for polymer dynamics have evolved the classical …