In-situ synthesis of molecular magnetorefrigerant materials

SJ Liu, SD Han, JP Zhao, J Xu, XH Bu - Coordination Chemistry Reviews, 2019 - Elsevier
Zero-dimensional cluster complexes and coordination polymers for magnetic refrigeration
have attracted great interest in the last decade. In-situ synthesis is a widely-used method to …

Magnetic cooling: a molecular perspective

P Konieczny, W Sas, D Czernia, A Pacanowska… - Dalton …, 2022 - pubs.rsc.org
The magnetocaloriceffect is considered as an energy-efficient and environmentally friendly
technique which can take cooling technology to the next level. Apart from its commercial …

Recent advances in 3d-4f magnetic complexes with several types of non-carboxylate organic ligands

HS Wang, K Zhang, Y Song, ZQ Pan - Inorganica Chimica Acta, 2021 - Elsevier
Since 1993, single molecule magnets (SMMs) have received a wide attention for their
potential applications in high-density information storage device, quantum computer and …

Magnetic materials based on heterometallic Cr II/III–Ln III complexes

P Shukla, S Das, P Bag, A Dey - Inorganic Chemistry Frontiers, 2023 - pubs.rsc.org
Accommodating disparate spin centres within a single ensemble is a valuable synthetic
strategy to obtain interesting molecular magnetic materials. 3d–4f heterometallic complexes …

Hourglass-Shaped Homo-and Heteronuclear Nonanuclear Lanthanide Clusters: Structures, Magnetism, Photoluminescence, and Theoretical Analysis

P Pandey, D Chauhan, MG Walawalkar… - Inorganic …, 2024 - ACS Publications
Synthesis of nonameric cationic clusters [Dy9 (acac) 16 (μ3-OH) 8 (μ4-OH) 2] OH· 6H2O
(1),[Dy8Tb (acac) 16 (μ3-OH) 8 (μ4-OH) 2] OH· 2H2O (2), and [Gd9 (acac) 16 (μ3-OH) 8 (μ4 …

The role of 3d–4f exchange interaction in SMM behaviour and magnetic refrigeration of carbonato bridged Cu II2 Ln III2 (Ln= Dy, Tb and Gd) complexes of an …

S Maity, A Mondal, S Konar, A Ghosh - Dalton Transactions, 2019 - pubs.rsc.org
The strategic design and synthesis of a new Cu (II) complex,[CuL](1) of an asymmetrically
dicondensed N2O4 donor ligand (where H2L= N-3-ethoxysalicylidene-N′-3 …

Exploiting Strong {CrIII–DyIII} Ferromagnetic Exchange Coupling to Quench Quantum Tunneling of Magnetization in a Novel {CrIII2DyIII3} Single-Molecule …

D Chauhan, KR Vignesh, A Swain… - Crystal Growth & …, 2022 - ACS Publications
The {3d–4f} pentanuclear complexes with the formula [CrIII2LnIII3 (PhCO2) 7 (OH) 6
(iPrO)(NO3)(H2O) 3](iPrO= isopropoxide)(where Ln= Dy (1), Gd (2)) have been synthesized …

Probing the Origin of Ferro-/Antiferromagnetic Exchange Interactions in Cu (II)–4f Complexes

N Ahmed, T Sharma, L Spillecke, C Koo… - Inorganic …, 2022 - ACS Publications
The mechanistic investigations between Cu (II) and the anisotropic lanthanides (Ln (III)) are
not much explored to date. This is due to the complicated energy spectrum which arises due …

Exchange-driven slow relaxation of magnetization in Ni II2 Ln III2 (Ln III= Y, Gd, Tb and Dy) butterfly complexes: experimental and theoretical studies

A Chakraborty, N Ahmed, J Ali, S Moorthy… - Dalton …, 2022 - pubs.rsc.org
The tetranuclear NiII2LnIII2 complexes,[{L′ 2 {Ni (MeOH)(μ-OAc)} 2 (μ3-MeO) 2Ln2}, LnIII=
YIII (1), GdIII (2), TbIII (3), and DyIII (4)], were prepared using a Schiff base ligand, H3L [H3L …

SMM behaviour of heterometallic dinuclear Cu II Ln III (Ln= Tb and Dy) complexes derived from N 2 O 3 donor unsymmetrical ligands

S Maity, P Bhunia, K Ichihashi, T Ishida… - New Journal of …, 2020 - pubs.rsc.org
Complexes [CuL1](1) and [CuL2](2) of two unsymmetrical N2O3 donor ligands (where H2L1
and H2L2 are N-salicylidene-N′-3-ethoxysalicylidene-1, 3-propanediamine and N …