Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

Ü Kökçam-Demir, A Goldman, L Esrafili… - Chemical Society …, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …

CO2 Capture and Separations Using MOFs: Computational and Experimental Studies

J Yu, LH **e, JR Li, Y Ma, JM Seminario… - Chemical …, 2017 - ACS Publications
This Review focuses on research oriented toward elucidation of the various aspects that
determine adsorption of CO2 in metal–organic frameworks and its separation from gas …

Metal–organic frameworks for air purification of toxic chemicals

JB DeCoste, GW Peterson - Chemical reviews, 2014 - ACS Publications
Since chlorine gas was first used in chemical warfare at Ypres, Belgium, in World War I
(WWI), the threat posed to military, civilian, and industrial personnel has continuously …

Application of a High-Throughput Analyzer in Evaluating Solid Adsorbents for Post-Combustion Carbon Capture via Multicomponent Adsorption of CO2, N2, and H2 …

JA Mason, TM McDonald, TH Bae… - Journal of the …, 2015 - ACS Publications
Despite the large number of metal–organic frameworks that have been studied in the context
of post-combustion carbon capture, adsorption equilibria of gas mixtures including CO2, N2 …

Selective adsorption of sulfur dioxide in a robust metal-organic framework material

M Savage, Y Cheng, TL Easun, JE Eyley… - Advanced …, 2016 - hal.science
Selective Adsorption of Sulfur Dioxide in a Robust Metal-Organic Framework Material Page 1
HAL Id: hal-01573030 https://hal.science/hal-01573030 Submitted on 8 Aug 2017 HAL is a …

Quantum-chemical characterization of the properties and reactivities of metal–organic frameworks

SO Odoh, CJ Cramer, DG Truhlar, L Gagliardi - Chemical reviews, 2015 - ACS Publications
The present review is concerned with quantum mechanical electronic structure calculations
on metal− organic frameworks (MOFs) to elucidate their properties and functionalities. There …

Near‐Zero Power MOF‐Based Sensors for NO2 Detection

LJ Small, SE Henkelis, DX Rademacher… - Advanced Functional …, 2020 - Wiley Online Library
Detection and capture of toxic nitrogen oxides (NOx) is important for emissions control of
exhaust gases and general public health. The ability to directly electrically detect trace (0.5 …

Adsorption of Phenol and p-Nitrophenol from Aqueous Solutions on Metal–Organic Frameworks: Effect of Hydrogen Bonding

B Liu, F Yang, Y Zou, Y Peng - Journal of Chemical & Engineering …, 2014 - ACS Publications
Three metal–organic frameworks (MOFs), MIL-100 (Fe, Cr) and NH2-MIL-101 (Al), were
prepared, and their adsorption equilibria for phenol and p-nitrophenol (PNP) from water …

Competitive Coadsorption of CO2 with H2O, NH3, SO2, NO, NO2, N2, O2, and CH4 in M-MOF-74 (M = Mg, Co, Ni): The Role of Hydrogen Bonding

K Tan, S Zuluaga, Q Gong, Y Gao, N Nijem… - Chemistry of …, 2015 - ACS Publications
The importance of coadsorption for applications of porous materials in gas separation has
motivated fundamental studies, which have initially focused on the comparison of the …

Metal–Organic Frameworks for NOx Adsorption and Their Applications in Separation, Sensing, Catalysis, and Biology

J Lin, W Ho, X Qin, CF Leung, VKM Au, S Lee - Small, 2022 - Wiley Online Library
Nitrogen oxide (NOx) is a family of poisonous and highly reactive gases formed when fuel is
burned at high temperatures during anthropogenic behavior. It is a strong oxidizing agent …