N-Heterocyclic carbenes (NHC) are nowadays ubiquitous and indispensable in many
research fields, and it is not possible to imagine modern transition metal and main group …

Complexes of metals with N-heterocyclic carbene ligands (M/NHC) are typically considered
the systems of choice in homogeneous catalysis due to their stable metal–ligand framework …

Summary Pnictinidenes (RE, where E= P, As, Sb, or Bi) are long-sought-after reactive
species. They feature either a singlet or triplet ground state depending on the electronic …

Herein, we report the synthesis of a sterically distorted distibene ([4] 2) and its transition‐
metal‐like reactivity towards two fundamental feedstock chemicals: H2 and ethylene …

Low-valent antimony and bismuth have emerged as novel platforms for achieving reversible
small-molecule activation at main-group metals. Although various examples of oxidative …

Local energy decomposition (LED) analysis decomposes the interaction energy between
two fragments calculated at the domain-based local pair natural orbital CCSD (T)(DLPNO …

Noncovalent interactions (NCIs) play a major role in essentially all fields of chemical
research. Energy decomposition analysis (EDA) schemes provide in‐depth insights into …

London dispersion (LD) interactions are the main contribution of the attractive part of the van
der Waals potential. Even though LD effects are the driving force for molecular aggregation …

Dipnictenes are molecules comprising a double bond between two Group 15 elements
(referred as pnictogens (Pn)= P, As, Sb, Bi). Over the last decades, the chemistry of …

Local energy decomposition analysis provides a breakdown of the domain‐based local pair
natural orbital CCSD (T)[DLPNO‐CCSD (T)] energy into additive contributions representing …