The aza‐ortho‐quinone methide (aza‐o‐QM) chemistry has overwhelmingly progressed in
the past few decades. This review aims to integrate various transition metal‐catalyzed and …

Arylation of carbonyls, one of the most common approaches toward alcohols, has received
tremendous attention, as alcohols are important feedstocks and building blocks in organic …

Over the past decades, the development of enantioselective catalysis using organocatalysts
has evolved into an active research field and a number of enantioselective transformations …

Alcohols and epoxides are arguably ideal electrophiles for the Friedel-Crafts alkylation,
since they are widely available, require no pre-activation, and produce no stoichiometric …

The past decade has seen a remarkable growth in the number of bioconjugation techniques
in chemistry, biology, material science, and biomedical fields. A core design element in …

A highly general and straightforward approach to access chiral bis (indolyl) methanes (BIMs)
bearing quaternary stereocenters has been realized via enantioconvergent dehydrative …

A catalytic protocol for a Friedel–Crafts-type direct C (sp2)–H methylation of various arenes
with methanol is disclosed. The reaction is initiated by counteranion-stabilized silylium or …

The catalytic deoxyamination of readily available 2‐arylethanols offers an appealing, simple,
and straightforward means of accessing β‐(hetero) arylethylamines of biological interest …

The regio-and chemoselective construction of indole bearing an all-carbon center at the C3-
position, a versatile bioactive building block, by C (sp2)–C (sp3) formation with olefins has …

Direct dehydroxytrifluoromethylthiolation of alcohols is an attractive strategy for accessing
CF3S-containing compounds. Herein, we report a method for …