Addressing the CO 2 challenge through thermocatalytic hydrogenation to carbon monoxide, methanol and methane

T Len, R Luque - Green Chemistry, 2023 - pubs.rsc.org
Carbon dioxide's impact on global warming is a problem that should be addressed in the
shortest term possible for the well-being of Earth's ecosystem and humanity. Among others …

Heterogeneous alkane dehydrogenation catalysts investigated via a surface organometallic chemistry approach

SR Docherty, L Rochlitz, PA Payard… - Chemical Society …, 2021 - pubs.rsc.org
The selective conversion of light alkanes (C2–C6 saturated hydrocarbons) to the
corresponding alkene is an appealing strategy for the petrochemical industry in view of the …

Advances in the Design of Heterogeneous Catalysts and Thermocatalytic Processes for CO2 Utilization

S De, A Dokania, A Ramirez, J Gascon - Acs Catalysis, 2020 - ACS Publications
Utilization of CO2 as feedstock to produce fine chemicals and renewable fuels is a highly
promising field, which presents unique challenges in its implementation at scale …

Unraveling surface structures of gallium promoted transition metal catalysts in CO2 hydrogenation

SW Lee, ML Luna, N Berdunov, W Wan… - Nature …, 2023 - nature.com
Gallium-containing alloys have recently been reported to hydrogenate CO2 to methanol at
ambient pressures. However, a full understanding of the Ga-promoted catalysts is still …

Deciphering Metal–Oxide and Metal–Metal Interplay via Surface Organometallic Chemistry: A Case Study with CO2 Hydrogenation to Methanol

SR Docherty, C Copéret - Journal of the American Chemical …, 2021 - ACS Publications
Processes that rely on heterogeneous catalysts underpin the production of bulk chemicals
and fuels. In spite of this, understanding of the interplay between the structure and reactivity …

Realizing synergy between Cu, Ga, and Zr for selective CO2 hydrogenation to methanol

AJ Al Abdulghani, EE Turizo-Pinilla… - Applied Catalysis B …, 2024 - Elsevier
Hydrogenating CO 2 to methanol with high yields and selectivity remains a kinetic
challenge. We report ternary Cu-Ga-Zr catalysts with promising performances. Methanol …

Structure and Role of a Ga-Promoter in Ni-Based Catalysts for the Selective Hydrogenation of CO2 to Methanol

NK Zimmerli, L Rochlitz, S Checchia, CR Müller… - JACS Au, 2024 - ACS Publications
Supported, bimetallic catalysts have shown great promise for the selective hydrogenation of
CO2 to methanol. In this study, we decipher the catalytically active structure of Ni–Ga-based …

Atom-by-atom design of Cu/ZrOx clusters on MgO for CO2 hydrogenation using liquid-phase atomic layer deposition

S **, C Kwon, A Bugaev, B Karakurt, YC Lin… - Nature Catalysis, 2024 - nature.com
The difficulty of synthesizing uniform atomically precise active sites limits our ability to
engineer increasingly more active heterogeneous catalysts for the hydrogenation of CO2 to …

Recent Advances in Alloy Catalysts for CO2 Hydrogenation to Methanol

B Gao, Z Wen, Y Wang, D Chen, B Yang… - …, 2024 - Wiley Online Library
The increasing anthropogenic carbon dioxide emissions (CO2) have a huge environmental
impact, and CO2 emission reduction is already a common view in our society. Recently …

Surface Redox Dynamics in Gold–Zinc CO2 Hydrogenation Catalysts

SR Docherty, OV Safonova… - Journal of the American …, 2023 - ACS Publications
Au–Zn catalysts have previously been shown to promote the hydrogenation of CO2 to
methanol, but their active state is poorly understood. Here, silica-supported bimetallic Au–Zn …